α-Scission of sulfonyl radicals: A versatile process for organic synthesis

Frédérique Bertrand; Frédéric Le Guyader; Lucia Liguori; Gilles Ouvry; Béatrice Quiclet-Sire; Stéphanie Seguin; Samir Z. Zard

doi:10.1016/S1387-1609(01)01270-1

α-Scission of sulfonyl radicals: A versatile process for organic synthesis

Frédérique Bertrand
, Frédéric Le Guyader
, Lucia Liguori
, Gilles Ouvry
, Béatrice Quiclet-Sire
, Stéphanie Seguin
, Samir Z. Zard

Research output: Contribution to journal › Review article › peer-review

Abstract

The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.

Original language	English
Pages (from-to)	547-555
Number of pages	9
Journal	Comptes Rendus de l'Academie des Sciences - Series IIc: Chemistry
Volume	4
Issue number	7
DOIs	https://doi.org/10.1016/S1387-1609(01)01270-1
Publication status	Published - 1 Jan 2001

Keywords

Alkylsulfonyl radicals
Alkynylation
Allylation
Azidation
Radical chains
Radicaux alkylsulfonyles
Radicaux trifluoromethanesulfonyles
Réactions radicalaires en chaîne
Trifluoromethanesulfonyl radicals
Vinylation

Access to Document

10.1016/S1387-1609(01)01270-1

Cite this

@article{3cba49dbcf5a423fb88a5c7603fdd8b3,

title = "α-Scission of sulfonyl radicals: A versatile process for organic synthesis",

abstract = "The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.",

keywords = "Alkylsulfonyl radicals, Alkynylation, Allylation, Azidation, Radical chains, Radicaux alkylsulfonyles, Radicaux trifluoromethanesulfonyles, R{\'e}actions radicalaires en cha{\^i}ne, Trifluoromethanesulfonyl radicals, Vinylation",

author = "Fr{\'e}d{\'e}rique Bertrand and \{Le Guyader\}, Fr{\'e}d{\'e}ric and Lucia Liguori and Gilles Ouvry and B{\'e}atrice Quiclet-Sire and St{\'e}phanie Seguin and Zard, \{Samir Z.\}",

year = "2001",

month = jan,

day = "1",

doi = "10.1016/S1387-1609(01)01270-1",

language = "English",

volume = "4",

pages = "547--555",

journal = "Comptes Rendus de l'Academie des Sciences - Series IIc: Chemistry",

issn = "1387-1609",

number = "7",

}

TY - JOUR

T1 - α-Scission of sulfonyl radicals

T2 - A versatile process for organic synthesis

AU - Bertrand, Frédérique

AU - Le Guyader, Frédéric

AU - Liguori, Lucia

AU - Ouvry, Gilles

AU - Quiclet-Sire, Béatrice

AU - Seguin, Stéphanie

AU - Zard, Samir Z.

PY - 2001/1/1

Y1 - 2001/1/1

N2 - The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.

AB - The reversible addition of aliphatic radicals to sulphur dioxide can be exploited to design a variety of tin-free chain reactions. This brief review summarises some of the possibilities, namely radical allylation, vinylation, alkynylation, and azidation of various substrates.

KW - Alkylsulfonyl radicals

KW - Alkynylation

KW - Allylation

KW - Azidation

KW - Radical chains

KW - Radicaux alkylsulfonyles

KW - Radicaux trifluoromethanesulfonyles

KW - Réactions radicalaires en chaîne

KW - Trifluoromethanesulfonyl radicals

KW - Vinylation

UR - https://www.scopus.com/pages/publications/0005348332

U2 - 10.1016/S1387-1609(01)01270-1

DO - 10.1016/S1387-1609(01)01270-1

M3 - Review article

AN - SCOPUS:0005348332

SN - 1387-1609

VL - 4

SP - 547

EP - 555

JO - Comptes Rendus de l'Academie des Sciences - Series IIc: Chemistry

JF - Comptes Rendus de l'Academie des Sciences - Series IIc: Chemistry

IS - 7

ER -

α-Scission of sulfonyl radicals: A versatile process for organic synthesis

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this