β-functionalized oligothiophenes for molecular self-assembly

R. Michalitsch; C. Nogues; A. Najari; A. Elkassmi; A. Yassar; P. Lang; F. Garnier

doi:10.1016/S0379-6779(98)00530-X

β-functionalized oligothiophenes for molecular self-assembly

R. Michalitsch
, C. Nogues
, A. Najari
, A. Elkassmi
, A. Yassar
, P. Lang
, F. Garnier

Centre national de la recherche scientifique

Research output: Contribution to journal › Conference article › peer-review

Abstract

Oligothiophenes carrying an alkylthiol group on one of the internal β-positions have been synthesized and adsorbed onto platinum and gold. The adsorbed assemblies are not very well organized, probably due to the geometry of the single molecules. The thiophene-based layers exhibit electrochemical activity in non aqueous electrolytes. The monomer units within the layers can be polymerized by a single anodic sweep. The obtained polymers show a high electrochemical and thermal stability. In some cases the polymer shows an increase of the structural order compared to the monomer layers.

Original language	English
Pages (from-to)	5-6
Number of pages	2
Journal	Synthetic Metals
Volume	101
Issue number	1
DOIs	https://doi.org/10.1016/S0379-6779(98)00530-X
Publication status	Published - 1 Jan 1999
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: 12 Jul 1998 → 18 Jul 1998

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title = "β-functionalized oligothiophenes for molecular self-assembly",

abstract = "Oligothiophenes carrying an alkylthiol group on one of the internal β-positions have been synthesized and adsorbed onto platinum and gold. The adsorbed assemblies are not very well organized, probably due to the geometry of the single molecules. The thiophene-based layers exhibit electrochemical activity in non aqueous electrolytes. The monomer units within the layers can be polymerized by a single anodic sweep. The obtained polymers show a high electrochemical and thermal stability. In some cases the polymer shows an increase of the structural order compared to the monomer layers.",

author = "R. Michalitsch and C. Nogues and A. Najari and A. Elkassmi and A. Yassar and P. Lang and F. Garnier",

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TY - JOUR

T1 - β-functionalized oligothiophenes for molecular self-assembly

AU - Michalitsch, R.

AU - Nogues, C.

AU - Najari, A.

AU - Elkassmi, A.

AU - Yassar, A.

AU - Lang, P.

AU - Garnier, F.

PY - 1999/1/1

Y1 - 1999/1/1

N2 - Oligothiophenes carrying an alkylthiol group on one of the internal β-positions have been synthesized and adsorbed onto platinum and gold. The adsorbed assemblies are not very well organized, probably due to the geometry of the single molecules. The thiophene-based layers exhibit electrochemical activity in non aqueous electrolytes. The monomer units within the layers can be polymerized by a single anodic sweep. The obtained polymers show a high electrochemical and thermal stability. In some cases the polymer shows an increase of the structural order compared to the monomer layers.

AB - Oligothiophenes carrying an alkylthiol group on one of the internal β-positions have been synthesized and adsorbed onto platinum and gold. The adsorbed assemblies are not very well organized, probably due to the geometry of the single molecules. The thiophene-based layers exhibit electrochemical activity in non aqueous electrolytes. The monomer units within the layers can be polymerized by a single anodic sweep. The obtained polymers show a high electrochemical and thermal stability. In some cases the polymer shows an increase of the structural order compared to the monomer layers.

U2 - 10.1016/S0379-6779(98)00530-X

DO - 10.1016/S0379-6779(98)00530-X

M3 - Conference article

AN - SCOPUS:0032597518

SN - 0379-6779

VL - 101

SP - 5

EP - 6

JO - Synthetic Metals

JF - Synthetic Metals

IS - 1

T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)

Y2 - 12 July 1998 through 18 July 1998

ER -

β-functionalized oligothiophenes for molecular self-assembly

Abstract

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