7.11 - N-Heterocyclic Carbene Complexes of Cobalt

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

Abstract

N-heterocyclic carbenes (NHCs) have become ubiquitous ligands across the Periodic Table and enjoy a growing impact on various aspects of the coordination, organometallic and catalytic chemistry of the 3d metals in particular, both from the fundamental viewpoint but also in applications, including catalysis, photophysics, bioorganometallic chemistry, materials etc. More specifically, this Chapter aims at a comprehensive coverage of the development and state of the art of cobalt NHC complexes. It is based on a recently published review on this topic (in Chem. Rev. 2019, 119, 3730−3961) and provides an update covering the literature until the end of 2020.

Original languageEnglish
Title of host publicationComprehensive Organometallic Chemistry IV
Subtitle of host publicationVolume 1-15
PublisherElsevier
PagesV7-632-V7-758
Volume7
ISBN (Electronic)9780128202067
DOIs
Publication statusPublished - 1 Jan 2022
Externally publishedYes

Keywords

  • Cobalt complexes
  • Coordination chemistry
  • Cyclic (alkyl)(amino)carbenes (cAAC)
  • Homogeneous catalysis
  • Imidazol(in)ylidene
  • Mesoionic carbenes
  • Molecular structures
  • N-heterocyclic carbenes
  • Organometallic chemistry
  • Pincer ligands
  • Reactivity
  • Synthesis
  • Triazolylidene

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