A 1,1'-ferrocenylene-bridged analogue of BIPNOR

Gilles Frison; Franck Brebion; Romain Dupont; F. Mercier; Louis Ricard; F. Mathey

doi:10.1016/S1631-0748(02)01366-8

A 1,1'-ferrocenylene-bridged analogue of BIPNOR

Gilles Frison
, Franck Brebion
, Romain Dupont
, F. Mercier
, Louis Ricard
, F. Mathey

CNRS

Research output: Contribution to journal › Article › peer-review

Abstract

At 170 °C, 1,1'-bis(3,4-dimethylphospholyl)ferrocene (7) isomerises through the corresponding 2H-phospholes that are trapped by diphenylacetylene to give the 1,1'-ferrocenylene-bridged bis-1-phosphanorbornadiene (6). After resolution with an optically pure palladium complex, (R, R)- and (S, S)-(6) are tested in the asymmetric hydrogenation of a dehydroaminoacid, hydroformylation of styrene, and allylation of sodium malonate.

Original language	English
Pages (from-to)	245-249
Number of pages	5
Journal	Comptes Rendus Chimie
Volume	5
Issue number	4
DOIs	https://doi.org/10.1016/S1631-0748(02)01366-8
Publication status	Published - 1 Jan 2002
Externally published	Yes

Keywords

Asymmetric Catalysis
Ferrocene
Phosphanorbornadiene
Phosphole

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10.1016/S1631-0748(02)01366-8

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title = "A 1,1'-ferrocenylene-bridged analogue of BIPNOR",

abstract = "At 170 °C, 1,1'-bis(3,4-dimethylphospholyl)ferrocene (7) isomerises through the corresponding 2H-phospholes that are trapped by diphenylacetylene to give the 1,1'-ferrocenylene-bridged bis-1-phosphanorbornadiene (6). After resolution with an optically pure palladium complex, (R, R)- and (S, S)-(6) are tested in the asymmetric hydrogenation of a dehydroaminoacid, hydroformylation of styrene, and allylation of sodium malonate.",

keywords = "Asymmetric Catalysis, Ferrocene, Phosphanorbornadiene, Phosphole",

author = "Gilles Frison and Franck Brebion and Romain Dupont and F. Mercier and Louis Ricard and F. Mathey",

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T1 - A 1,1'-ferrocenylene-bridged analogue of BIPNOR

AU - Frison, Gilles

AU - Brebion, Franck

AU - Dupont, Romain

AU - Mercier, F.

AU - Ricard, Louis

AU - Mathey, F.

PY - 2002/1/1

Y1 - 2002/1/1

N2 - At 170 °C, 1,1'-bis(3,4-dimethylphospholyl)ferrocene (7) isomerises through the corresponding 2H-phospholes that are trapped by diphenylacetylene to give the 1,1'-ferrocenylene-bridged bis-1-phosphanorbornadiene (6). After resolution with an optically pure palladium complex, (R, R)- and (S, S)-(6) are tested in the asymmetric hydrogenation of a dehydroaminoacid, hydroformylation of styrene, and allylation of sodium malonate.

AB - At 170 °C, 1,1'-bis(3,4-dimethylphospholyl)ferrocene (7) isomerises through the corresponding 2H-phospholes that are trapped by diphenylacetylene to give the 1,1'-ferrocenylene-bridged bis-1-phosphanorbornadiene (6). After resolution with an optically pure palladium complex, (R, R)- and (S, S)-(6) are tested in the asymmetric hydrogenation of a dehydroaminoacid, hydroformylation of styrene, and allylation of sodium malonate.

KW - Asymmetric Catalysis

KW - Ferrocene

KW - Phosphanorbornadiene

KW - Phosphole

UR - https://www.scopus.com/pages/publications/0036965145

U2 - 10.1016/S1631-0748(02)01366-8

DO - 10.1016/S1631-0748(02)01366-8

M3 - Article

AN - SCOPUS:0036965145

SN - 1631-0748

VL - 5

SP - 245

EP - 249

JO - Comptes Rendus Chimie

JF - Comptes Rendus Chimie

IS - 4

ER -

A 1,1'-ferrocenylene-bridged analogue of BIPNOR

Abstract

Keywords

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