A convergent, modular access to complex amines

Béatrice Quiclet-Sire; Guillaume Revol; Samir Z. Zard

doi:10.1016/j.tet.2010.05.107

A convergent, modular access to complex amines

Béatrice Quiclet-Sire
, Guillaume Revol
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

62 Citations (Scopus)

Abstract

Various xanthates can be added to N-vinyl phthalimide with little formation of oligomers, if the xanthate is used in excess and the medium slightly diluted. The adduct xanthates thus obtained can in turn undergo radical additions to numerous olefins, providing a convergent and modular access to densely functionalized amines.

Original language	English
Pages (from-to)	6656-6666
Number of pages	11
Journal	Tetrahedron
Volume	66
Issue number	33
DOIs	https://doi.org/10.1016/j.tet.2010.05.107
Publication status	Published - 14 Aug 2010
Externally published	Yes

Keywords

Amines
Phthalimides
Radical addition
Xanthates

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10.1016/j.tet.2010.05.107

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title = "A convergent, modular access to complex amines",

abstract = "Various xanthates can be added to N-vinyl phthalimide with little formation of oligomers, if the xanthate is used in excess and the medium slightly diluted. The adduct xanthates thus obtained can in turn undergo radical additions to numerous olefins, providing a convergent and modular access to densely functionalized amines.",

keywords = "Amines, Phthalimides, Radical addition, Xanthates",

author = "B{\'e}atrice Quiclet-Sire and Guillaume Revol and Zard, \{Samir Z.\}",

year = "2010",

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day = "14",

doi = "10.1016/j.tet.2010.05.107",

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journal = "Tetrahedron",

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T1 - A convergent, modular access to complex amines

AU - Quiclet-Sire, Béatrice

AU - Revol, Guillaume

AU - Zard, Samir Z.

PY - 2010/8/14

Y1 - 2010/8/14

N2 - Various xanthates can be added to N-vinyl phthalimide with little formation of oligomers, if the xanthate is used in excess and the medium slightly diluted. The adduct xanthates thus obtained can in turn undergo radical additions to numerous olefins, providing a convergent and modular access to densely functionalized amines.

AB - Various xanthates can be added to N-vinyl phthalimide with little formation of oligomers, if the xanthate is used in excess and the medium slightly diluted. The adduct xanthates thus obtained can in turn undergo radical additions to numerous olefins, providing a convergent and modular access to densely functionalized amines.

KW - Amines

KW - Phthalimides

KW - Radical addition

KW - Xanthates

U2 - 10.1016/j.tet.2010.05.107

DO - 10.1016/j.tet.2010.05.107

M3 - Article

AN - SCOPUS:77955654398

SN - 0040-4020

VL - 66

SP - 6656

EP - 6666

JO - Tetrahedron

JF - Tetrahedron

IS - 33

ER -

A convergent, modular access to complex amines

Abstract

Keywords

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