A convergent radical-based route to biaryls

Béatrice Quiclet-Sire; Guillaume Revol; Samlr Z. Zard

doi:10.1021/ol9010294

A convergent radical-based route to biaryls

Béatrice Quiclet-Sire
, Guillaume Revol
, Samlr Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

A route to blaryl-3-carboxylate esters Involving a radical 1,2-aryl migration has been developed. This strategy hinges on the radical addition of xanthate 2 to olefin 1 causing a 1,2-aryl shift leading to α,β- unsaturated ester 5, which Is then converted Into blaryl 10 by treatment with DBU under microwave heating

Original language	English
Pages (from-to)	2832-2835
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	13
DOIs	https://doi.org/10.1021/ol9010294
Publication status	Published - 2 Jul 2009
Externally published	Yes

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10.1021/ol9010294

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@article{5a4bbd02404240c7a12ea6db2af211eb,

title = "A convergent radical-based route to biaryls",

abstract = "A route to blaryl-3-carboxylate esters Involving a radical 1,2-aryl migration has been developed. This strategy hinges on the radical addition of xanthate 2 to olefin 1 causing a 1,2-aryl shift leading to α,β- unsaturated ester 5, which Is then converted Into blaryl 10 by treatment with DBU under microwave heating",

author = "B{\'e}atrice Quiclet-Sire and Guillaume Revol and Zard, \{Samlr Z.\}",

year = "2009",

month = jul,

day = "2",

doi = "10.1021/ol9010294",

language = "English",

volume = "11",

pages = "2832--2835",

journal = "Organic Letters",

issn = "1523-7060",

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T1 - A convergent radical-based route to biaryls

AU - Quiclet-Sire, Béatrice

AU - Revol, Guillaume

AU - Zard, Samlr Z.

PY - 2009/7/2

Y1 - 2009/7/2

N2 - A route to blaryl-3-carboxylate esters Involving a radical 1,2-aryl migration has been developed. This strategy hinges on the radical addition of xanthate 2 to olefin 1 causing a 1,2-aryl shift leading to α,β- unsaturated ester 5, which Is then converted Into blaryl 10 by treatment with DBU under microwave heating

AB - A route to blaryl-3-carboxylate esters Involving a radical 1,2-aryl migration has been developed. This strategy hinges on the radical addition of xanthate 2 to olefin 1 causing a 1,2-aryl shift leading to α,β- unsaturated ester 5, which Is then converted Into blaryl 10 by treatment with DBU under microwave heating

U2 - 10.1021/ol9010294

DO - 10.1021/ol9010294

M3 - Article

C2 - 19492807

AN - SCOPUS:67649518186

SN - 1523-7060

VL - 11

SP - 2832

EP - 2835

JO - Organic Letters

JF - Organic Letters

IS - 13

ER -

A convergent radical-based route to biaryls

Abstract

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