A direct approach to α-hydroxy and α-chloro trifluoromethyl derivatives

Lucie Tournier; Samir Z. Zard

doi:10.1016/j.tetlet.2004.11.086

A direct approach to α-hydroxy and α-chloro trifluoromethyl derivatives

Lucie Tournier
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2-trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide. S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2- trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide.

Original language	English
Pages (from-to)	455-459
Number of pages	5
Journal	Tetrahedron Letters
Volume	46
Issue number	3
DOIs	https://doi.org/10.1016/j.tetlet.2004.11.086
Publication status	Published - 17 Jan 2005
Externally published	Yes

Keywords

Dithiocarbonate
Radical chain reaction
Trifluoromethyl

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10.1016/j.tetlet.2004.11.086

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title = "A direct approach to α-hydroxy and α-chloro trifluoromethyl derivatives",

abstract = "S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2-trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide. S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2- trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide.",

keywords = "Dithiocarbonate, Radical chain reaction, Trifluoromethyl",

author = "Lucie Tournier and Zard, \{Samir Z.\}",

year = "2005",

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day = "17",

doi = "10.1016/j.tetlet.2004.11.086",

language = "English",

volume = "46",

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journal = "Tetrahedron Letters",

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T1 - A direct approach to α-hydroxy and α-chloro trifluoromethyl derivatives

AU - Tournier, Lucie

AU - Zard, Samir Z.

PY - 2005/1/17

Y1 - 2005/1/17

N2 - S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2-trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide. S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2- trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide.

AB - S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2-trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide. S-1-Acyloxy-2,2,2-trifluoroethyl and S-1-chloro-2,2,2- trifluoroethyl dithiocarbonates add efficiently to various functionalised olefins to give the corresponding adducts via a radical chain reaction initiated by a small amount of lauroyl peroxide.

KW - Dithiocarbonate

KW - Radical chain reaction

KW - Trifluoromethyl

UR - https://www.scopus.com/pages/publications/11144250890

U2 - 10.1016/j.tetlet.2004.11.086

DO - 10.1016/j.tetlet.2004.11.086

M3 - Article

AN - SCOPUS:11144250890

SN - 0040-4039

VL - 46

SP - 455

EP - 459

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 3

ER -

A direct approach to α-hydroxy and α-chloro trifluoromethyl derivatives

Abstract

Keywords

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