A direct approach to α-trifluoromethylamines

Fabien Gagosz; Samir Z. Zard

doi:10.1021/ol034812m

A direct approach to α-trifluoromethylamines

Fabien Gagosz
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

(Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.

Original language	English
Pages (from-to)	2655-2657
Number of pages	3
Journal	Organic Letters
Volume	5
Issue number	15
DOIs	https://doi.org/10.1021/ol034812m
Publication status	Published - 24 Jul 2003
Externally published	Yes

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@article{b27c85a62d0d4bfcaa00fe54f1403308,

title = "A direct approach to α-trifluoromethylamines",

abstract = "(Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.",

author = "Fabien Gagosz and Zard, \{Samir Z.\}",

year = "2003",

month = jul,

day = "24",

doi = "10.1021/ol034812m",

language = "English",

volume = "5",

pages = "2655--2657",

journal = "Organic Letters",

issn = "1523-7060",

number = "15",

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T1 - A direct approach to α-trifluoromethylamines

AU - Gagosz, Fabien

AU - Zard, Samir Z.

PY - 2003/7/24

Y1 - 2003/7/24

N2 - (Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.

AB - (Matrix presented) S-[1-(N-Acetylamino)-2,2,2-trifluoroethyl]-O-ethyl dithiocarbonate (6), a readily available xanthate, adds efficiently to various functionalized olefins to give the corresponding adducts 8 via a radical chain reaction initiated by a small amount of lauroyl peroxide.

U2 - 10.1021/ol034812m

DO - 10.1021/ol034812m

M3 - Article

AN - SCOPUS:0141631561

SN - 1523-7060

VL - 5

SP - 2655

EP - 2657

JO - Organic Letters

JF - Organic Letters

IS - 15

ER -

A direct approach to α-trifluoromethylamines

Abstract

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