A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

David Clemente-Tejeda; Juan Carlos Ortiz Lara; Samir Z. Zard

doi:10.1055/s-0035-1562449

A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

David Clemente-Tejeda
, Juan Carlos Ortiz Lara
, Samir Z. Zard

Laboratoire de Synthèse Organique
Sintenovo S.A de C.v.

Research output: Contribution to journal › Article › peer-review

Abstract

The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.

Original language	English
Article number	ss-2016-c0375-op
Pages (from-to)	3393-3399
Number of pages	7
Journal	Synthesis
Volume	48
Issue number	19
DOIs	https://doi.org/10.1055/s-0035-1562449
Publication status	Published - 4 Oct 2016
Externally published	Yes

Keywords

S -propargyl xanthate
esters
inversion
propionates
sigmatropic rearrangement

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10.1055/s-0035-1562449

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title = "A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate",

abstract = "The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.",

keywords = "S -propargyl xanthate, esters, inversion, propionates, sigmatropic rearrangement",

author = "David Clemente-Tejeda and Lara, \{Juan Carlos Ortiz\} and Zard, \{Samir Z.\}",

note = "Publisher Copyright: {\textcopyright} Georg Thieme Verlag Stuttgart New York.",

year = "2016",

month = oct,

day = "4",

doi = "10.1055/s-0035-1562449",

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T1 - A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

AU - Clemente-Tejeda, David

AU - Lara, Juan Carlos Ortiz

AU - Zard, Samir Z.

N1 - Publisher Copyright: © Georg Thieme Verlag Stuttgart New York.

PY - 2016/10/4

Y1 - 2016/10/4

N2 - The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.

AB - The S-propargyl xanthate derived from ethyl (S)-lactate reacts upon heating with various acidic substances to give the propionate transfer product in high yield and with complete inversion of configuration.

KW - S -propargyl xanthate

KW - esters

KW - inversion

KW - propionates

KW - sigmatropic rearrangement

U2 - 10.1055/s-0035-1562449

DO - 10.1055/s-0035-1562449

M3 - Article

AN - SCOPUS:84978493443

SN - 0039-7881

VL - 48

SP - 3393

EP - 3399

JO - Synthesis

JF - Synthesis

IS - 19

M1 - ss-2016-c0375-op

ER -

A Direct Approach to Enantiopure Propionate Derivatives from Ethyl Lactate

Abstract

Keywords

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