A direct, versatile route to functionalized trialkoxysilanes

Béatrice Quiclet-Sire; Yuuki Yanagisawa; Samir Z. Zard

doi:10.1039/c3cc48570f

A direct, versatile route to functionalized trialkoxysilanes

Béatrice Quiclet-Sire
, Yuuki Yanagisawa
, Samir Z. Zard

Research output: Contribution to journal › Article › peer-review

Abstract

The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.

Original language	English
Pages (from-to)	2324-2326
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	18
DOIs	https://doi.org/10.1039/c3cc48570f
Publication status	Published - 4 Feb 2014
Externally published	Yes

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title = "A direct, versatile route to functionalized trialkoxysilanes",

abstract = "The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.",

author = "B{\'e}atrice Quiclet-Sire and Yuuki Yanagisawa and Zard, \{Samir Z.\}",

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AU - Quiclet-Sire, Béatrice

AU - Yanagisawa, Yuuki

AU - Zard, Samir Z.

PY - 2014/2/4

Y1 - 2014/2/4

N2 - The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.

AB - The peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkoxy vinylsilanes leads to functionalized trialkoxysilanes. Prior addition of the dithiocarbonates to an alkene before reaction with the vinylsilane can be used to increase the complexity of the final product.

U2 - 10.1039/c3cc48570f

DO - 10.1039/c3cc48570f

M3 - Article

AN - SCOPUS:84893635003

SN - 1359-7345

VL - 50

SP - 2324

EP - 2326

JO - Chemical Communications

JF - Chemical Communications

IS - 18

ER -

A direct, versatile route to functionalized trialkoxysilanes

Abstract

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