A highly conjunctive β-keto phosphonate: Application to the synthesis of pyridine alkaloids xestamines C, E, and H

Matthieu Corbet; Michiel De Greet; Samir Z. Zard

doi:10.1021/ol702590f

A highly conjunctive β-keto phosphonate: Application to the synthesis of pyridine alkaloids xestamines C, E, and H

Matthieu Corbet, Michiel De Greet, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

(Chemical Equation Presented) The synthesis of a novel β-keto γ-xanthyl phosphonate has been achieved. This highly conjunctive reagent has been utilized in a combination of radical and ionic reactions to create new carbon-carbon bonds. Its usefulness was demonstrated by realizing the first total synthesis of naturally occurring pyridine alkaloids xestamines C, E, and H.

Original language	English
Pages (from-to)	253-256
Number of pages	4
Journal	Organic Letters
Volume	10
Issue number	2
DOIs	https://doi.org/10.1021/ol702590f
Publication status	Published - 17 Jan 2008
Externally published	Yes

Access to Document

10.1021/ol702590f

Cite this

@article{2b13b87457e44695b1bad79a08552e68,

title = "A highly conjunctive β-keto phosphonate: Application to the synthesis of pyridine alkaloids xestamines C, E, and H",

abstract = "(Chemical Equation Presented) The synthesis of a novel β-keto γ-xanthyl phosphonate has been achieved. This highly conjunctive reagent has been utilized in a combination of radical and ionic reactions to create new carbon-carbon bonds. Its usefulness was demonstrated by realizing the first total synthesis of naturally occurring pyridine alkaloids xestamines C, E, and H.",

author = "Matthieu Corbet and \{De Greet\}, Michiel and Zard, \{Samir Z.\}",

year = "2008",

month = jan,

day = "17",

doi = "10.1021/ol702590f",

language = "English",

volume = "10",

pages = "253--256",

journal = "Organic Letters",

issn = "1523-7060",

number = "2",

}

TY - JOUR

T1 - A highly conjunctive β-keto phosphonate

T2 - Application to the synthesis of pyridine alkaloids xestamines C, E, and H

AU - Corbet, Matthieu

AU - De Greet, Michiel

AU - Zard, Samir Z.

PY - 2008/1/17

Y1 - 2008/1/17

N2 - (Chemical Equation Presented) The synthesis of a novel β-keto γ-xanthyl phosphonate has been achieved. This highly conjunctive reagent has been utilized in a combination of radical and ionic reactions to create new carbon-carbon bonds. Its usefulness was demonstrated by realizing the first total synthesis of naturally occurring pyridine alkaloids xestamines C, E, and H.

AB - (Chemical Equation Presented) The synthesis of a novel β-keto γ-xanthyl phosphonate has been achieved. This highly conjunctive reagent has been utilized in a combination of radical and ionic reactions to create new carbon-carbon bonds. Its usefulness was demonstrated by realizing the first total synthesis of naturally occurring pyridine alkaloids xestamines C, E, and H.

U2 - 10.1021/ol702590f

DO - 10.1021/ol702590f

M3 - Article

C2 - 18161980

AN - SCOPUS:38749121374

SN - 1523-7060

VL - 10

SP - 253

EP - 256

JO - Organic Letters

JF - Organic Letters

IS - 2

ER -

A highly conjunctive β-keto phosphonate: Application to the synthesis of pyridine alkaloids xestamines C, E, and H

Abstract

Access to Document

Fingerprint

Cite this