A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M-R to vanadate oxo

Mu Jeng Cheng; Robert J. Nielsen; William A. Goddard

doi:10.1039/c4cc03067b

A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M-R to vanadate oxo

Mu Jeng Cheng
, Robert J. Nielsen
, William A. Goddard

California Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A new mechanism for generating C-O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C-O bond in phenol formed by the reaction of OVCl₃ with HgPh₂, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

Original language	English
Pages (from-to)	10994-10996
Number of pages	3
Journal	Chemical Communications
Volume	50
Issue number	75
DOIs	https://doi.org/10.1039/c4cc03067b
Publication status	Published - 21 Aug 2014
Externally published	Yes

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title = "A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M-R to vanadate oxo",

abstract = "A new mechanism for generating C-O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C-O bond in phenol formed by the reaction of OVCl3 with HgPh2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.",

author = "Cheng, \{Mu Jeng\} and Nielsen, \{Robert J.\} and Goddard, \{William A.\}",

year = "2014",

month = aug,

day = "21",

doi = "10.1039/c4cc03067b",

language = "English",

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T2 - intermolecular hydrocarbyl migration from M-R to vanadate oxo

AU - Cheng, Mu Jeng

AU - Nielsen, Robert J.

AU - Goddard, William A.

PY - 2014/8/21

Y1 - 2014/8/21

N2 - A new mechanism for generating C-O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C-O bond in phenol formed by the reaction of OVCl3 with HgPh2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

AB - A new mechanism for generating C-O bonds from metal-hydrocarbyls involving homolytic, intermolecular migration of the hydrocarbyl group to a vanadium oxo is reported. Responsible for the C-O bond in phenol formed by the reaction of OVCl3 with HgPh2, it may provide air-regenerable metal oxos a role in aerobic alkane oxidations.

U2 - 10.1039/c4cc03067b

DO - 10.1039/c4cc03067b

M3 - Article

AN - SCOPUS:84906535626

SN - 1359-7345

VL - 50

SP - 10994

EP - 10996

JO - Chemical Communications

JF - Chemical Communications

IS - 75

ER -

A homolytic oxy-functionalization mechanism: intermolecular hydrocarbyl migration from M-R to vanadate oxo

Abstract

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