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A model of the Earth's Dole effect

  • Georg Hoffmann
  • , Matthias Cuntz
  • , Christine Weber
  • , Philippe Ciais
  • , Pierre Friedlingstein
  • , Martin Heimann
  • , Jean Jouzel
  • , Jörg Kaduk
  • , Ernst Maier-Reimer
  • , Ulrike Seibt
  • , Katharina Six
  • Service d'Aéronomie
  • UVSQ
  • Max Planck Institute for Meteorology
  • Max Planck Institute for Biogeochemistry
  • University of Leicester

Research output: Contribution to journalArticlepeer-review

Abstract

The Earth's Dole effect describes the isotopic 18O/16O-enrichment of atmospheric oxygen with respect to ocean water, amounting under today's conditions to 23.5‰. We have developed a model of the Earth's Dole effect by combining the results of three-dimensional models of the oceanic and terrestrial carbon and oxygen cycles with results of atmospheric general circulation models (AGCMs) with built-in water isotope diagnostics. We obtain a range from 22.4‰ to 23.3‰ for the isotopic enrichment of atmospheric oxygen. We estimate a stronger contribution to the global Dole effect by the terrestrial relative to the marine biosphere in contrast to previous studies. This is primarily caused by a modeled high leaf water enrichment of 5-6‰. Leaf water enrichment rises by ∼1‰ to 6-7‰ when we use it to fit the observed 23.5‰ of the global Dole effect. The present model is designed to be utilized in forthcoming paleo studies allowing a quantitative analysis of long-term observations from polar ice cores.

Original languageEnglish
Pages (from-to)GB1008 1-15
JournalGlobal Biogeochemical Cycles
Volume18
Issue number1
DOIs
Publication statusPublished - 1 Jan 2004
Externally publishedYes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

  1. SDG 14 - Life Below Water
    SDG 14 Life Below Water

Keywords

  • Carbon cycle
  • Dole effect
  • Water isotopes

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