A new approach to the synthesis of polycyclic structures

Michael E. Briggs; Myriem El Qacemi; Chakib Kalaï; Samir Z. Zard

doi:10.1016/j.tetlet.2004.06.035

A new approach to the synthesis of polycyclic structures

Michael E. Briggs
, Myriem El Qacemi
, Chakib Kalaï
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

22 Citations (Scopus)

Abstract

A general, convergent approach to the synthesis of polycyclic structures has been developed, based on the tandem radical addition/cyclisation of xanthates to dienones followed by an ionic ring closure to give, finally, a number of variously substituted tricyclic compounds.

Original language	English
Pages (from-to)	6017-6020
Number of pages	4
Journal	Tetrahedron Letters
Volume	45
Issue number	31
DOIs	https://doi.org/10.1016/j.tetlet.2004.06.035
Publication status	Published - 26 Jul 2004
Externally published	Yes

Keywords

Radical cascades
Robinson annelation
Xanthate addition

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10.1016/j.tetlet.2004.06.035

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title = "A new approach to the synthesis of polycyclic structures",

abstract = "A general, convergent approach to the synthesis of polycyclic structures has been developed, based on the tandem radical addition/cyclisation of xanthates to dienones followed by an ionic ring closure to give, finally, a number of variously substituted tricyclic compounds.",

keywords = "Radical cascades, Robinson annelation, Xanthate addition",

author = "Briggs, \{Michael E.\} and \{El Qacemi\}, Myriem and Chakib Kala{\"i} and Zard, \{Samir Z.\}",

year = "2004",

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T1 - A new approach to the synthesis of polycyclic structures

AU - Briggs, Michael E.

AU - El Qacemi, Myriem

AU - Kalaï, Chakib

AU - Zard, Samir Z.

PY - 2004/7/26

Y1 - 2004/7/26

N2 - A general, convergent approach to the synthesis of polycyclic structures has been developed, based on the tandem radical addition/cyclisation of xanthates to dienones followed by an ionic ring closure to give, finally, a number of variously substituted tricyclic compounds.

AB - A general, convergent approach to the synthesis of polycyclic structures has been developed, based on the tandem radical addition/cyclisation of xanthates to dienones followed by an ionic ring closure to give, finally, a number of variously substituted tricyclic compounds.

KW - Radical cascades

KW - Robinson annelation

KW - Xanthate addition

U2 - 10.1016/j.tetlet.2004.06.035

DO - 10.1016/j.tetlet.2004.06.035

M3 - Article

AN - SCOPUS:3142661111

SN - 0040-4039

VL - 45

SP - 6017

EP - 6020

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

A new approach to the synthesis of polycyclic structures

Abstract

Keywords

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