A new, practical access to amidyl radicals

Cécile Moutrille; Samir Z. Zard

doi:10.1039/b405545d

A new, practical access to amidyl radicals

Cécile Moutrille
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

Amidyl radicals are readily generated from N-allylsulfonimides by the action of a xanthate and a small amount of a peroxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond; in some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap.

Original language	English
Pages (from-to)	1848-1849
Number of pages	2
Journal	Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/b405545d
Publication status	Published - 21 Aug 2004
Externally published	Yes

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title = "A new, practical access to amidyl radicals",

abstract = "Amidyl radicals are readily generated from N-allylsulfonimides by the action of a xanthate and a small amount of a peroxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond; in some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap.",

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AU - Zard, Samir Z.

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AB - Amidyl radicals are readily generated from N-allylsulfonimides by the action of a xanthate and a small amount of a peroxide as initiator. The process involves extrusion of sulfur dioxide from an N-amidosulfonyl radical by rupture of the nitrogen-sulfur bond; in some cases, the N-amidosulfonyl radical is prematurely captured by the internal olefinic trap.

U2 - 10.1039/b405545d

DO - 10.1039/b405545d

M3 - Article

AN - SCOPUS:4644334178

SN - 1359-7345

SP - 1848

EP - 1849

JO - Chemical Communications

JF - Chemical Communications

IS - 16

ER -

A new, practical access to amidyl radicals

Abstract

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