A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

Jonathan Axon; Laurent Boiteau; Jean Boivin; Judith E. Forbes; Samir Z. Zard

doi:10.1016/0040-4039(94)88328-9

A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

Jonathan Axon
, Laurent Boiteau
, Jean Boivin
, Judith E. Forbes
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

72 Citations (Scopus)

Abstract

N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.

Original language	English
Pages (from-to)	1719-1722
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	11
DOIs	https://doi.org/10.1016/0040-4039(94)88328-9
Publication status	Published - 14 Mar 1994
Externally published	Yes

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@article{00f25e3a13894d8bac0578e5e385a810,

title = "A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)",

abstract = "N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.",

author = "Jonathan Axon and Laurent Boiteau and Jean Boivin and Forbes, \{Judith E.\} and Zard, \{Samir Z.\}",

year = "1994",

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T1 - A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

AU - Axon, Jonathan

AU - Boiteau, Laurent

AU - Boivin, Jean

AU - Forbes, Judith E.

AU - Zard, Samir Z.

PY - 1994/3/14

Y1 - 1994/3/14

N2 - N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.

AB - N,N-disubstituted a-(xanthyl)-acetamides with an olefin on one of the substituents undergo cyclisation to a lactam by a radical chain reaction involving transfer of the xanthate group; anilides lead to the corresponding indolones.

U2 - 10.1016/0040-4039(94)88328-9

DO - 10.1016/0040-4039(94)88328-9

M3 - Article

AN - SCOPUS:0028314798

SN - 0040-4039

VL - 35

SP - 1719

EP - 1722

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 11

ER -

A new radical based synthesis of lactams and indolones from dithiocarbonates (xanthates)

Abstract

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