A new radical vinylation reaction of iodides and dithiocarbonates

Frédérique Bertrand; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

A new radical vinylation reaction of iodides and dithiocarbonates

Frédérique Bertrand
, Béatrice Quiclet-Sire
, Samir Z. Zard

Institut de Chimie des Substances Naturelles
Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.

Original language	English
Pages (from-to)	1943-1946
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	13-14
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R
Publication status	Published - 12 Jul 1999
Externally published	Yes

Keywords

Alkenes
Allylation
C-C coupling
Radical reactions
Vinyl sulfones

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10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

Cite this

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title = "A new radical vinylation reaction of iodides and dithiocarbonates",

abstract = "Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.",

keywords = "Alkenes, Allylation, C-C coupling, Radical reactions, Vinyl sulfones",

author = "Fr{\'e}d{\'e}rique Bertrand and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "1999",

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AU - Bertrand, Frédérique

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 1999/7/12

Y1 - 1999/7/12

N2 - Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.

AB - Heavy metals can be avoided with a new radical equivalent of the Heck reaction for aliphatic derivatives in which iodide and dithiocarbonate substituents are replaced by substituted vinyl groups [Eq.(1)]. The reaction enables the introduction of vinyl fragments into a variety of functionalized substrates.

KW - Alkenes

KW - Allylation

KW - C-C coupling

KW - Radical reactions

KW - Vinyl sulfones

UR - https://www.scopus.com/pages/publications/0033549583

U2 - 10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

DO - 10.1002/(SICI)1521-3773(19990712)38:13/14<1943::AID-ANIE1943>3.0.CO;2-R

M3 - Article

AN - SCOPUS:0033549583

SN - 1433-7851

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EP - 1946

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 13-14

ER -

A new radical vinylation reaction of iodides and dithiocarbonates

Abstract

Keywords

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