A new, simple, efficient electrosynthesis of functionalized benzylic zinc species and their reactivity toward aromatic aldehydes

C. Gosmini; Y. Rollin; C. Gebehenne; E. Lojou; V. Ratovelomanana; J. Périchon

doi:10.1016/S0040-4039(00)77267-4

A new, simple, efficient electrosynthesis of functionalized benzylic zinc species and their reactivity toward aromatic aldehydes

C. Gosmini
, Y. Rollin
, C. Gebehenne
, E. Lojou
, V. Ratovelomanana
, J. Périchon

Centre national de la recherche scientifique

Research output: Contribution to journal › Article › peer-review

Abstract

Various stable substituted benzylic zincs are formed in acetonitrile upon reaction of the bromide derivatives, in good yields, using a catalytic electrogenerated zinc species associated with massive zinc. In the presence of chlorotrimethylsilane, these organozincs react instantaneously with functionalized aromatic aldehydes.

Original language	English
Pages (from-to)	5637-5640
Number of pages	4
Journal	Tetrahedron Letters
Volume	35
Issue number	31
DOIs	https://doi.org/10.1016/S0040-4039(00)77267-4
Publication status	Published - 1 Aug 1994

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title = "A new, simple, efficient electrosynthesis of functionalized benzylic zinc species and their reactivity toward aromatic aldehydes",

abstract = "Various stable substituted benzylic zincs are formed in acetonitrile upon reaction of the bromide derivatives, in good yields, using a catalytic electrogenerated zinc species associated with massive zinc. In the presence of chlorotrimethylsilane, these organozincs react instantaneously with functionalized aromatic aldehydes.",

author = "C. Gosmini and Y. Rollin and C. Gebehenne and E. Lojou and V. Ratovelomanana and J. P{\'e}richon",

year = "1994",

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T1 - A new, simple, efficient electrosynthesis of functionalized benzylic zinc species and their reactivity toward aromatic aldehydes

AU - Gosmini, C.

AU - Rollin, Y.

AU - Gebehenne, C.

AU - Lojou, E.

AU - Ratovelomanana, V.

AU - Périchon, J.

PY - 1994/8/1

Y1 - 1994/8/1

N2 - Various stable substituted benzylic zincs are formed in acetonitrile upon reaction of the bromide derivatives, in good yields, using a catalytic electrogenerated zinc species associated with massive zinc. In the presence of chlorotrimethylsilane, these organozincs react instantaneously with functionalized aromatic aldehydes.

AB - Various stable substituted benzylic zincs are formed in acetonitrile upon reaction of the bromide derivatives, in good yields, using a catalytic electrogenerated zinc species associated with massive zinc. In the presence of chlorotrimethylsilane, these organozincs react instantaneously with functionalized aromatic aldehydes.

U2 - 10.1016/S0040-4039(00)77267-4

DO - 10.1016/S0040-4039(00)77267-4

M3 - Article

AN - SCOPUS:0027966202

SN - 0040-4039

VL - 35

SP - 5637

EP - 5640

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 31

ER -

A new, simple, efficient electrosynthesis of functionalized benzylic zinc species and their reactivity toward aromatic aldehydes

Abstract

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