A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

Bernard Barlaam; Jean Boivin; Samir Z. Zard

doi:10.1016/S0040-4039(00)77482-X

A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

Bernard Barlaam
, Jean Boivin
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

13 Citations (Scopus)

Abstract

Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.

Original language	English
Pages (from-to)	1023-1026
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	6
DOIs	https://doi.org/10.1016/S0040-4039(00)77482-X
Publication status	Published - 5 Feb 1993
Externally published	Yes

Keywords

Allylic nitro compounds
chromous acetate.
dienes
reduction

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10.1016/S0040-4039(00)77482-X

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@article{efd4d73be05c4bffa9e31996fdc30789,

title = "A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives",

abstract = "Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.",

keywords = "Allylic nitro compounds, chromous acetate., dienes, reduction",

author = "Bernard Barlaam and Jean Boivin and Zard, \{Samir Z.\}",

year = "1993",

month = feb,

day = "5",

doi = "10.1016/S0040-4039(00)77482-X",

language = "English",

volume = "34",

pages = "1023--1026",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "6",

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TY - JOUR

T1 - A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

AU - Barlaam, Bernard

AU - Boivin, Jean

AU - Zard, Samir Z.

PY - 1993/2/5

Y1 - 1993/2/5

N2 - Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.

AB - Tertiary allylic nitro compounds, bearing an acetate or a mesylate in β position smoothly undergo a reductive elimination to give conjugated 1,3 dienes when treated with chromous acetate/ 2,2′-dipyridyl in DMF at 110-120°C.

KW - Allylic nitro compounds

KW - chromous acetate.

KW - dienes

KW - reduction

U2 - 10.1016/S0040-4039(00)77482-X

DO - 10.1016/S0040-4039(00)77482-X

M3 - Article

AN - SCOPUS:0027466697

SN - 0040-4039

VL - 34

SP - 1023

EP - 1026

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 6

ER -

A new synthesis of substituted dienes by reductive elimination of allylic nitro derivatives

Abstract

Keywords

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