A nitrido-centered uranium azido cluster obtained from a uranium azide

Grégory Nocton; Jacques Pécaut; Marinella Mazzanti

doi:10.1002/anie.200705742

A nitrido-centered uranium azido cluster obtained from a uranium azide

Grégory Nocton
, Jacques Pécaut
, Marinella Mazzanti

Univ. Joseph Fourier-Grenoble 1

Research output: Contribution to journal › Article › peer-review

111 Citations (Scopus)

Abstract

(Figure Presented) Caught in the actinide: A tetranuclear azido/nitrido uranium anion containing eight end-on bridging azido ligands and a μ₄ interstitial nitrido ligand has been isolatedand structurally characterized (see 1D chain; U green, Cs orange, I magenta, N blue, C white). A new two-step procedure has been developed to promote the cluster assembly by oxidation of [UI₃-(thf)₅] with a preformeduranium heptaazido complex.

Original language	English
Pages (from-to)	3040-3042
Number of pages	3
Journal	Angewandte Chemie - International Edition
Volume	47
Issue number	16
DOIs	https://doi.org/10.1002/anie.200705742
Publication status	Published - 7 Apr 2008
Externally published	Yes

Keywords

Actinides
Azides
Cluster compounds
Nitrides
Uranium

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10.1002/anie.200705742

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abstract = "(Figure Presented) Caught in the actinide: A tetranuclear azido/nitrido uranium anion containing eight end-on bridging azido ligands and a μ4 interstitial nitrido ligand has been isolatedand structurally characterized (see 1D chain; U green, Cs orange, I magenta, N blue, C white). A new two-step procedure has been developed to promote the cluster assembly by oxidation of [UI3-(thf)5] with a preformeduranium heptaazido complex.",

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author = "Gr{\'e}gory Nocton and Jacques P{\'e}caut and Marinella Mazzanti",

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T1 - A nitrido-centered uranium azido cluster obtained from a uranium azide

AU - Nocton, Grégory

AU - Pécaut, Jacques

AU - Mazzanti, Marinella

PY - 2008/4/7

Y1 - 2008/4/7

N2 - (Figure Presented) Caught in the actinide: A tetranuclear azido/nitrido uranium anion containing eight end-on bridging azido ligands and a μ4 interstitial nitrido ligand has been isolatedand structurally characterized (see 1D chain; U green, Cs orange, I magenta, N blue, C white). A new two-step procedure has been developed to promote the cluster assembly by oxidation of [UI3-(thf)5] with a preformeduranium heptaazido complex.

AB - (Figure Presented) Caught in the actinide: A tetranuclear azido/nitrido uranium anion containing eight end-on bridging azido ligands and a μ4 interstitial nitrido ligand has been isolatedand structurally characterized (see 1D chain; U green, Cs orange, I magenta, N blue, C white). A new two-step procedure has been developed to promote the cluster assembly by oxidation of [UI3-(thf)5] with a preformeduranium heptaazido complex.

KW - Actinides

KW - Azides

KW - Cluster compounds

KW - Nitrides

KW - Uranium

U2 - 10.1002/anie.200705742

DO - 10.1002/anie.200705742

M3 - Article

AN - SCOPUS:52649120627

SN - 1433-7851

VL - 47

SP - 3040

EP - 3042

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 16

ER -

A nitrido-centered uranium azido cluster obtained from a uranium azide

Abstract

Keywords

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