A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

Cédric Tard; Xiaoming Liu; David L. Hughes; Christopher J. Pickett

doi:10.1039/b411559g

A novel {Fe^I-Fe^II-Fe^II-Fe^I} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

Cédric Tard
, Xiaoming Liu
, David L. Hughes
, Christopher J. Pickett

John Innes Centre
Department of Biological Chemistry

Research output: Contribution to journal › Article › peer-review

65 Citations (Scopus)

Abstract

A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a 'butterfly' configuration of the {2Fe3S}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal-metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.

Original language	English
Pages (from-to)	133-135
Number of pages	3
Journal	Chemical Communications
Issue number	1
DOIs	https://doi.org/10.1039/b411559g
Publication status	Published - 7 Jan 2005
Externally published	Yes

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title = "A novel \{FeI-FeII-FeII-FeI\} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution",

abstract = "A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a 'butterfly' configuration of the \{2Fe3S\}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal-metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.",

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AU - Tard, Cédric

AU - Liu, Xiaoming

AU - Hughes, David L.

AU - Pickett, Christopher J.

PY - 2005/1/7

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AB - A novel tetra-iron thiolate carbonyl assembly is described in which two dithiolate tetracarbonyl di-iron centres with a 'butterfly' configuration of the {2Fe3S}-cores are fused by two bridging thiolates which form a central planar 2Fe2S unit and comprise the first example of a chain of four metal-metal bonded iron atoms supported by a bridging sulfur framework; the assembly electrocatalyses hydrogen evolution.

U2 - 10.1039/b411559g

DO - 10.1039/b411559g

M3 - Article

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JO - Chemical Communications

JF - Chemical Communications

IS - 1

ER -

A novel {FeI-FeII-FeII-FeI} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution

Abstract

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A novel {Fe^I-Fe^II-Fe^II-Fe^I} iron thiolate carbonyl assembly which electrocatalyses hydrogen evolution