A novel radical chain reaction of xanthic anhydrides. Further observations on the intermediacy of alkoxy-thiocarbonyl radicals in the Barton-McCombie reaction

J. E. Forbes; S. Z. Zard

doi:10.1016/S0040-4039(00)99362-6

A novel radical chain reaction of xanthic anhydrides. Further observations on the intermediacy of alkoxy-thiocarbonyl radicals in the Barton-McCombie reaction

J. E. Forbes
, S. Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

On irradiation with visible light, primary and secondary xanthic anhydrides undergo a radical chain reaction to give the corresponding xanthates with loss of carbon oxysulphide.

Original language	English
Pages (from-to)	4367-4370
Number of pages	4
Journal	Tetrahedron Letters
Volume	30
Issue number	33
DOIs	https://doi.org/10.1016/S0040-4039(00)99362-6
Publication status	Published - 1 Jan 1989
Externally published	Yes

Access to Document

10.1016/S0040-4039(00)99362-6

Cite this

@article{991241d9b7d6431a8957d2d41238e37d,

title = "A novel radical chain reaction of xanthic anhydrides. Further observations on the intermediacy of alkoxy-thiocarbonyl radicals in the Barton-McCombie reaction",

abstract = "On irradiation with visible light, primary and secondary xanthic anhydrides undergo a radical chain reaction to give the corresponding xanthates with loss of carbon oxysulphide.",

author = "Forbes, \{J. E.\} and Zard, \{S. Z.\}",

year = "1989",

month = jan,

day = "1",

doi = "10.1016/S0040-4039(00)99362-6",

language = "English",

volume = "30",

pages = "4367--4370",

journal = "Tetrahedron Letters",

issn = "0040-4039",

number = "33",

}

TY - JOUR

T1 - A novel radical chain reaction of xanthic anhydrides. Further observations on the intermediacy of alkoxy-thiocarbonyl radicals in the Barton-McCombie reaction

AU - Forbes, J. E.

AU - Zard, S. Z.

PY - 1989/1/1

Y1 - 1989/1/1

N2 - On irradiation with visible light, primary and secondary xanthic anhydrides undergo a radical chain reaction to give the corresponding xanthates with loss of carbon oxysulphide.

AB - On irradiation with visible light, primary and secondary xanthic anhydrides undergo a radical chain reaction to give the corresponding xanthates with loss of carbon oxysulphide.

UR - https://www.scopus.com/pages/publications/0000634612

U2 - 10.1016/S0040-4039(00)99362-6

DO - 10.1016/S0040-4039(00)99362-6

M3 - Article

AN - SCOPUS:0000634612

SN - 0040-4039

VL - 30

SP - 4367

EP - 4370

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 33

ER -

A novel radical chain reaction of xanthic anhydrides. Further observations on the intermediacy of alkoxy-thiocarbonyl radicals in the Barton-McCombie reaction

Abstract

Access to Document

Other files and links

Fingerprint

Cite this