A novel synthesis of 13-dithiol-2-ones from S-propargyl dithiocarbonates

Jean Boivin; Eric Henriet; Catherine Tailhan; Samir Z. Zard

doi:10.1016/S0040-4039(00)73556-8

A novel synthesis of 13-dithiol-2-ones from S-propargyl dithiocarbonates

Jean Boivin
, Eric Henriet
, Catherine Tailhan
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Upon heating in chlorobenzene in the presence of a carboxylic acid, propargylic xanthates 1b-h give the corresponding 1,3-dithiol-2-ones 10b-h and/or 11b-h, the former being easily isomerised to the latter with hot trifluoroacetic acid.

Original language	English
Pages (from-to)	2763-2766
Number of pages	4
Journal	Tetrahedron Letters
Volume	34
Issue number	17
DOIs	https://doi.org/10.1016/S0040-4039(00)73556-8
Publication status	Published - 23 Apr 1993
Externally published	Yes

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title = "A novel synthesis of 13-dithiol-2-ones from S-propargyl dithiocarbonates",

abstract = "Upon heating in chlorobenzene in the presence of a carboxylic acid, propargylic xanthates 1b-h give the corresponding 1,3-dithiol-2-ones 10b-h and/or 11b-h, the former being easily isomerised to the latter with hot trifluoroacetic acid.",

author = "Jean Boivin and Eric Henriet and Catherine Tailhan and Zard, \{Samir Z.\}",

year = "1993",

month = apr,

day = "23",

doi = "10.1016/S0040-4039(00)73556-8",

language = "English",

volume = "34",

pages = "2763--2766",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier Ltd",

number = "17",

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TY - JOUR

T1 - A novel synthesis of 13-dithiol-2-ones from S-propargyl dithiocarbonates

AU - Boivin, Jean

AU - Henriet, Eric

AU - Tailhan, Catherine

AU - Zard, Samir Z.

PY - 1993/4/23

Y1 - 1993/4/23

N2 - Upon heating in chlorobenzene in the presence of a carboxylic acid, propargylic xanthates 1b-h give the corresponding 1,3-dithiol-2-ones 10b-h and/or 11b-h, the former being easily isomerised to the latter with hot trifluoroacetic acid.

AB - Upon heating in chlorobenzene in the presence of a carboxylic acid, propargylic xanthates 1b-h give the corresponding 1,3-dithiol-2-ones 10b-h and/or 11b-h, the former being easily isomerised to the latter with hot trifluoroacetic acid.

U2 - 10.1016/S0040-4039(00)73556-8

DO - 10.1016/S0040-4039(00)73556-8

M3 - Article

AN - SCOPUS:0027267391

SN - 0040-4039

VL - 34

SP - 2763

EP - 2766

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 17

ER -

A novel synthesis of 13-dithiol-2-ones from S-propargyl dithiocarbonates

Abstract

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