A practical variation on the Leuckart reaction

Lucie Tournier; Samir Z. Zard

doi:10.1016/j.tetlet.2004.12.042

A practical variation on the Leuckart reaction

Lucie Tournier
, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

S-Aryldiazo xanthates, derived from the corresponding diazonium salts by reaction with potassium O-ethyl xanthate, undergo a radical chain reaction with loss of nitrogen; the intermediate aromatic radical can be captured by an internal olefin to give bicyclic xanthates in good overall yield.

Original language	English
Pages (from-to)	971-973
Number of pages	3
Journal	Tetrahedron Letters
Volume	46
Issue number	6
DOIs	https://doi.org/10.1016/j.tetlet.2004.12.042
Publication status	Published - 7 Feb 2005
Externally published	Yes

Keywords

Aromatic radical
Diazonium salt
Leuckart reaction
Xanthate

Access to Document

10.1016/j.tetlet.2004.12.042

Cite this

@article{ea346d91c05744ad8f1420e943129b9c,

title = "A practical variation on the Leuckart reaction",

abstract = "S-Aryldiazo xanthates, derived from the corresponding diazonium salts by reaction with potassium O-ethyl xanthate, undergo a radical chain reaction with loss of nitrogen; the intermediate aromatic radical can be captured by an internal olefin to give bicyclic xanthates in good overall yield.",

keywords = "Aromatic radical, Diazonium salt, Leuckart reaction, Xanthate",

author = "Lucie Tournier and Zard, \{Samir Z.\}",

year = "2005",

month = feb,

day = "7",

doi = "10.1016/j.tetlet.2004.12.042",

language = "English",

volume = "46",

pages = "971--973",

journal = "Tetrahedron Letters",

issn = "0040-4039",

number = "6",

}

TY - JOUR

T1 - A practical variation on the Leuckart reaction

AU - Tournier, Lucie

AU - Zard, Samir Z.

PY - 2005/2/7

Y1 - 2005/2/7

N2 - S-Aryldiazo xanthates, derived from the corresponding diazonium salts by reaction with potassium O-ethyl xanthate, undergo a radical chain reaction with loss of nitrogen; the intermediate aromatic radical can be captured by an internal olefin to give bicyclic xanthates in good overall yield.

AB - S-Aryldiazo xanthates, derived from the corresponding diazonium salts by reaction with potassium O-ethyl xanthate, undergo a radical chain reaction with loss of nitrogen; the intermediate aromatic radical can be captured by an internal olefin to give bicyclic xanthates in good overall yield.

KW - Aromatic radical

KW - Diazonium salt

KW - Leuckart reaction

KW - Xanthate

U2 - 10.1016/j.tetlet.2004.12.042

DO - 10.1016/j.tetlet.2004.12.042

M3 - Article

AN - SCOPUS:12344268872

SN - 0040-4039

VL - 46

SP - 971

EP - 973

JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 6

ER -

A practical variation on the Leuckart reaction

Abstract

Keywords

Access to Document

Fingerprint

Cite this