Abstract
Geminal mercapto trialkyl- and trialkoxy-silanes undergo an efficient radical chain rearrangement, whereby the silyl group migrates from carbon to sulfur; the starting materials are readily obtained by exploiting the peroxide initiated radical addition of dithiocarbonates (xanthates) to trialkyl- or trialkoxy-vinylsilanes.
| Original language | English |
|---|---|
| Pages (from-to) | 5990-5992 |
| Number of pages | 3 |
| Journal | Chemical Communications |
| Volume | 50 |
| Issue number | 45 |
| DOIs | |
| Publication status | Published - 8 May 2014 |
| Externally published | Yes |