Abstract
A short formal total synthesis of (±)-hirsutic acid is described using a Claisen rearrangement and a radical cascade as the key steps. The radical sequence involves an intermolecular addition of a radical derived from a xanthate followed by a cyclization and transfer of the xanthate group.
| Original language | English |
|---|---|
| Pages (from-to) | 927-931 |
| Number of pages | 5 |
| Journal | Canadian Journal of Chemistry |
| Volume | 90 |
| Issue number | 11 |
| DOIs | |
| Publication status | Published - 30 Nov 2012 |
| Externally published | Yes |
Keywords
- Claisen rearrangement
- Complicatic acid
- Hirsutic acid
- Radical cyclization
- Triquinanes
- Xanthates
Fingerprint
Dive into the research topics of 'A short formal total synthesis of (±)-hirsutic acid'. Together they form a unique fingerprint.Cite this
- APA
- Author
- BIBTEX
- Harvard
- Standard
- RIS
- Vancouver