A short synthesis of (±)-matrine [2]

Laurent Boiteau; Jean Boivin; Annie Liard; Béatrice Quiclet-Sire; Samir Z. Zard

doi:10.1002/(SICI)1521-3773(19980504)37:8<1128::AID-ANIE1128>3.0.CO;2-P

A short synthesis of (±)-matrine [2]

Laurent Boiteau
, Jean Boivin
, Annie Liard
, Béatrice Quiclet-Sire
, Samir Z. Zard

Research output: Contribution to journal › Article › peer-review

Abstract

Three different radical reactions were used in a short total synthesis of (±)-matrine (1). Two of the four six-membered rings and four new bonds were created in one radical cascade involving intermolecular addition followed by two successive cyclizations and transfer of a xanthate group.

Original language	English
Pages (from-to)	1128-1131
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	37
Issue number	8
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19980504)37:8<1128::AID-ANIE1128>3.0.CO;2-P
Publication status	Published - 4 May 1998
Externally published	Yes

Keywords

Cyclizations
Domino reactions
Matrine
Natural products
Radical reactions

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10.1002/(SICI)1521-3773(19980504)37:8<1128::AID-ANIE1128>3.0.CO;2-P

Cite this

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title = "A short synthesis of (±)-matrine [2]",

abstract = "Three different radical reactions were used in a short total synthesis of (±)-matrine (1). Two of the four six-membered rings and four new bonds were created in one radical cascade involving intermolecular addition followed by two successive cyclizations and transfer of a xanthate group.",

keywords = "Cyclizations, Domino reactions, Matrine, Natural products, Radical reactions",

author = "Laurent Boiteau and Jean Boivin and Annie Liard and B{\'e}atrice Quiclet-Sire and Zard, \{Samir Z.\}",

year = "1998",

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T1 - A short synthesis of (±)-matrine [2]

AU - Boiteau, Laurent

AU - Boivin, Jean

AU - Liard, Annie

AU - Quiclet-Sire, Béatrice

AU - Zard, Samir Z.

PY - 1998/5/4

Y1 - 1998/5/4

N2 - Three different radical reactions were used in a short total synthesis of (±)-matrine (1). Two of the four six-membered rings and four new bonds were created in one radical cascade involving intermolecular addition followed by two successive cyclizations and transfer of a xanthate group.

AB - Three different radical reactions were used in a short total synthesis of (±)-matrine (1). Two of the four six-membered rings and four new bonds were created in one radical cascade involving intermolecular addition followed by two successive cyclizations and transfer of a xanthate group.

KW - Cyclizations

KW - Domino reactions

KW - Matrine

KW - Natural products

KW - Radical reactions

U2 - 10.1002/(SICI)1521-3773(19980504)37:8<1128::AID-ANIE1128>3.0.CO;2-P

DO - 10.1002/(SICI)1521-3773(19980504)37:8<1128::AID-ANIE1128>3.0.CO;2-P

M3 - Article

AN - SCOPUS:0032482096

SN - 1433-7851

VL - 37

SP - 1128

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 8

ER -

A short synthesis of (±)-matrine [2]

Abstract

Keywords

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