A short total synthesis of estrone derivatives: A novel 1,3-rearrangement of an allylic nitro group

Bernard Barlaam; Jean Boivin; Laurent Elkaim; Sarah Elton-Farr; Samir Z. Zard

doi:10.1016/0040-4020(94)01034-W

A short total synthesis of estrone derivatives: A novel 1,3-rearrangement of an allylic nitro group

Bernard Barlaam, Jean Boivin, Laurent Elkaim, Sarah Elton-Farr, Samir Z. Zard

Laboratoire de Synthèse Organique

Research output: Contribution to journal › Article › peer-review

Abstract

Racemic 11β, 14β-dihydroxyestrone has been preparared from 6-methoxytetralone in 5 steps involving a new acid catalysed 1,3-shift of an allylic nitro group.

Original language	English
Pages (from-to)	1675-1684
Number of pages	10
Journal	Tetrahedron
Volume	51
Issue number	6
DOIs	https://doi.org/10.1016/0040-4020(94)01034-W
Publication status	Published - 6 Feb 1995
Externally published	Yes

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@article{e3aae45dde684ce193e5cfb2a0c087d6,

title = "A short total synthesis of estrone derivatives: A novel 1,3-rearrangement of an allylic nitro group",

abstract = "Racemic 11β, 14β-dihydroxyestrone has been preparared from 6-methoxytetralone in 5 steps involving a new acid catalysed 1,3-shift of an allylic nitro group.",

author = "Bernard Barlaam and Jean Boivin and Laurent Elkaim and Sarah Elton-Farr and Zard, \{Samir Z.\}",

year = "1995",

month = feb,

day = "6",

doi = "10.1016/0040-4020(94)01034-W",

language = "English",

volume = "51",

pages = "1675--1684",

journal = "Tetrahedron",

issn = "0040-4020",

number = "6",

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TY - JOUR

T1 - A short total synthesis of estrone derivatives

T2 - A novel 1,3-rearrangement of an allylic nitro group

AU - Barlaam, Bernard

AU - Boivin, Jean

AU - Elkaim, Laurent

AU - Elton-Farr, Sarah

AU - Zard, Samir Z.

PY - 1995/2/6

Y1 - 1995/2/6

N2 - Racemic 11β, 14β-dihydroxyestrone has been preparared from 6-methoxytetralone in 5 steps involving a new acid catalysed 1,3-shift of an allylic nitro group.

AB - Racemic 11β, 14β-dihydroxyestrone has been preparared from 6-methoxytetralone in 5 steps involving a new acid catalysed 1,3-shift of an allylic nitro group.

U2 - 10.1016/0040-4020(94)01034-W

DO - 10.1016/0040-4020(94)01034-W

M3 - Article

AN - SCOPUS:0028857520

SN - 0040-4020

VL - 51

SP - 1675

EP - 1684

JO - Tetrahedron

JF - Tetrahedron

IS - 6

ER -

A short total synthesis of estrone derivatives: A novel 1,3-rearrangement of an allylic nitro group

Abstract

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