Alkylation of C60. Reaction between C60 anions and tert-butyl chloride and mass spectrometry analysis

S. Bourcier; P. Chaurand; C. Ciot; S. Della-Negra; C. Fabre; V. Greugny; L. Marx; A. Rassat; A. Rousseau

doi:10.1016/s0168-1176(96)04414-x

Alkylation of C₆₀. Reaction between C₆₀ anions and tert-butyl chloride and mass spectrometry analysis

S. Bourcier
, P. Chaurand
, C. Ciot
, S. Della-Negra
, C. Fabre
, V. Greugny
, L. Marx
, A. Rassat
, A. Rousseau

Université Paris-Sud
Centre de Recherche de Vitry-Alfortville
PSL research University & IPSL
Univ. Joseph Fourier-Grenoble 1

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

Alkylation of C₆₀ in tetrahydrofuran with tert-butyl chloride and lithium gives a variety of products. Adducts of general formula C₆₀H_n(t-Bu)_qO_x(thf)_y (where t-Bu is the tert-butyl group and thf the tetrahydrofuryl group (C₄H₇O)) have been detected by mass spectrometry, with n ≤ 8, q + y ≤ 18 and x = 0, 1, 2 depending on experimental conditions. IR and NMR spectra of products confirm these assignments.

Original language	English
Pages (from-to)	85-101
Number of pages	17
Journal	International Journal of Mass Spectrometry and Ion Processes
Volume	156
Issue number	1-2
DOIs	https://doi.org/10.1016/s0168-1176(96)04414-x
Publication status	Published - 1 Jan 1996

Keywords

Alkylation
C

Access to Document

10.1016/s0168-1176(96)04414-x

Cite this

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title = "Alkylation of C60. Reaction between C60 anions and tert-butyl chloride and mass spectrometry analysis",

abstract = "Alkylation of C60 in tetrahydrofuran with tert-butyl chloride and lithium gives a variety of products. Adducts of general formula C60Hn(t-Bu)qOx(thf)y (where t-Bu is the tert-butyl group and thf the tetrahydrofuryl group (C4H7O)) have been detected by mass spectrometry, with n ≤ 8, q + y ≤ 18 and x = 0, 1, 2 depending on experimental conditions. IR and NMR spectra of products confirm these assignments.",

keywords = "Alkylation, C",

author = "S. Bourcier and P. Chaurand and C. Ciot and S. Della-Negra and C. Fabre and V. Greugny and L. Marx and A. Rassat and A. Rousseau",

year = "1996",

month = jan,

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doi = "10.1016/s0168-1176(96)04414-x",

language = "English",

volume = "156",

pages = "85--101",

journal = "International Journal of Mass Spectrometry and Ion Processes",

issn = "0168-1176",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Alkylation of C60. Reaction between C60 anions and tert-butyl chloride and mass spectrometry analysis

AU - Bourcier, S.

AU - Chaurand, P.

AU - Ciot, C.

AU - Della-Negra, S.

AU - Fabre, C.

AU - Greugny, V.

AU - Marx, L.

AU - Rassat, A.

AU - Rousseau, A.

PY - 1996/1/1

Y1 - 1996/1/1

N2 - Alkylation of C60 in tetrahydrofuran with tert-butyl chloride and lithium gives a variety of products. Adducts of general formula C60Hn(t-Bu)qOx(thf)y (where t-Bu is the tert-butyl group and thf the tetrahydrofuryl group (C4H7O)) have been detected by mass spectrometry, with n ≤ 8, q + y ≤ 18 and x = 0, 1, 2 depending on experimental conditions. IR and NMR spectra of products confirm these assignments.

AB - Alkylation of C60 in tetrahydrofuran with tert-butyl chloride and lithium gives a variety of products. Adducts of general formula C60Hn(t-Bu)qOx(thf)y (where t-Bu is the tert-butyl group and thf the tetrahydrofuryl group (C4H7O)) have been detected by mass spectrometry, with n ≤ 8, q + y ≤ 18 and x = 0, 1, 2 depending on experimental conditions. IR and NMR spectra of products confirm these assignments.

KW - Alkylation

KW - C

U2 - 10.1016/s0168-1176(96)04414-x

DO - 10.1016/s0168-1176(96)04414-x

M3 - Article

AN - SCOPUS:30844437523

SN - 0168-1176

VL - 156

SP - 85

EP - 101

JO - International Journal of Mass Spectrometry and Ion Processes

JF - International Journal of Mass Spectrometry and Ion Processes

IS - 1-2