Allylation of carbonyl compounds by allylic acetates using a cobalt halide as catalyst

Paulo Gomes; Corinne Gosmini; Jacques Périchon

doi:10.1055/s-2003-40999

Allylation of carbonyl compounds by allylic acetates using a cobalt halide as catalyst

Paulo Gomes
, Corinne Gosmini
, Jacques Périchon

Centre national de la recherche scientifique

Research output: Contribution to journal › Article › peer-review

Abstract

In acetonitrile as solvent and in the presence of a simple cobalt halide as catalyst, the reduction by zinc dust of a mixture of aldehydes or ketones and allylic acetates affords the corresponding homoallylic alcohols in good yields.

Original language	English
Pages (from-to)	1909-1915
Number of pages	7
Journal	Synthesis
Issue number	12
DOIs	https://doi.org/10.1055/s-2003-40999
Publication status	Published - 1 Jan 2003

Keywords

Allylation
Carbonyl copmounds
Catalyst
Cobalt halide
Homo-allylic alcohols

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10.1055/s-2003-40999

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title = "Allylation of carbonyl compounds by allylic acetates using a cobalt halide as catalyst",

abstract = "In acetonitrile as solvent and in the presence of a simple cobalt halide as catalyst, the reduction by zinc dust of a mixture of aldehydes or ketones and allylic acetates affords the corresponding homoallylic alcohols in good yields.",

keywords = "Allylation, Carbonyl copmounds, Catalyst, Cobalt halide, Homo-allylic alcohols",

author = "Paulo Gomes and Corinne Gosmini and Jacques P{\'e}richon",

year = "2003",

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day = "1",

doi = "10.1055/s-2003-40999",

language = "English",

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journal = "Synthesis",

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T1 - Allylation of carbonyl compounds by allylic acetates using a cobalt halide as catalyst

AU - Gomes, Paulo

AU - Gosmini, Corinne

AU - Périchon, Jacques

PY - 2003/1/1

Y1 - 2003/1/1

N2 - In acetonitrile as solvent and in the presence of a simple cobalt halide as catalyst, the reduction by zinc dust of a mixture of aldehydes or ketones and allylic acetates affords the corresponding homoallylic alcohols in good yields.

AB - In acetonitrile as solvent and in the presence of a simple cobalt halide as catalyst, the reduction by zinc dust of a mixture of aldehydes or ketones and allylic acetates affords the corresponding homoallylic alcohols in good yields.

KW - Allylation

KW - Carbonyl copmounds

KW - Catalyst

KW - Cobalt halide

KW - Homo-allylic alcohols

U2 - 10.1055/s-2003-40999

DO - 10.1055/s-2003-40999

M3 - Article

AN - SCOPUS:0141519409

SN - 0039-7881

SP - 1909

EP - 1915

JO - Synthesis

JF - Synthesis

IS - 12

ER -

Allylation of carbonyl compounds by allylic acetates using a cobalt halide as catalyst

Abstract

Keywords

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