An η2 transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)5], dppe = 1,2-bis(diphenylphosphanyl)ethane

Duncan Carmichael; Peter B. Hitchcock; John F. Nixon; François Mathey; Louis Ricard

doi:10.1039/C39890001389

An η² transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)₅], dppe = 1,2-bis(diphenylphosphanyl)ethane

Duncan Carmichael
, Peter B. Hitchcock
, John F. Nixon
, François Mathey
, Louis Ricard

University of Sussex
CNRS

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Evidence for a transition state involving η² co-ordination of a P-C bond to [Pd(dppe)] is obtained from an analysis of the insertion of [Pd(dppe)] fragments into (E)- and (Z)- [W(CO)₅(PPh-CHPh-CHPh)] complexes.

Original language	English
Pages (from-to)	1389-1390
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	18
DOIs	https://doi.org/10.1039/C39890001389
Publication status	Published - 1 Jan 1989
Externally published	Yes

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Carmichael, D., Hitchcock, P. B., Nixon, J. F., Mathey, F., & Ricard, L. (1989). An η² transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)₅], dppe = 1,2-bis(diphenylphosphanyl)ethane. Journal of the Chemical Society, Chemical Communications, (18), 1389-1390. https://doi.org/10.1039/C39890001389

Carmichael, Duncan ; Hitchcock, Peter B. ; Nixon, John F. et al. / An η² transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)₅], dppe = 1,2-bis(diphenylphosphanyl)ethane. In: Journal of the Chemical Society, Chemical Communications. 1989 ; No. 18. pp. 1389-1390.

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title = "An η2 transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)5], dppe = 1,2-bis(diphenylphosphanyl)ethane",

abstract = "Evidence for a transition state involving η2 co-ordination of a P-C bond to [Pd(dppe)] is obtained from an analysis of the insertion of [Pd(dppe)] fragments into (E)- and (Z)- [W(CO)5(PPh-CHPh-CHPh)] complexes.",

author = "Duncan Carmichael and Hitchcock, \{Peter B.\} and Nixon, \{John F.\} and Fran{\c c}ois Mathey and Louis Ricard",

year = "1989",

month = jan,

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doi = "10.1039/C39890001389",

language = "English",

pages = "1389--1390",

journal = "Journal of the Chemical Society, Chemical Communications",

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Carmichael, D, Hitchcock, PB, Nixon, JF, Mathey, F & Ricard, L 1989, 'An η² transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)₅], dppe = 1,2-bis(diphenylphosphanyl)ethane', Journal of the Chemical Society, Chemical Communications, no. 18, pp. 1389-1390. https://doi.org/10.1039/C39890001389

An η² transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)₅], dppe = 1,2-bis(diphenylphosphanyl)ethane. / Carmichael, Duncan; Hitchcock, Peter B.; Nixon, John F. et al.
In: Journal of the Chemical Society, Chemical Communications, No. 18, 01.01.1989, p. 1389-1390.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - An η2 transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)5], dppe = 1,2-bis(diphenylphosphanyl)ethane

AU - Carmichael, Duncan

AU - Hitchcock, Peter B.

AU - Nixon, John F.

AU - Mathey, François

AU - Ricard, Louis

PY - 1989/1/1

Y1 - 1989/1/1

N2 - Evidence for a transition state involving η2 co-ordination of a P-C bond to [Pd(dppe)] is obtained from an analysis of the insertion of [Pd(dppe)] fragments into (E)- and (Z)- [W(CO)5(PPh-CHPh-CHPh)] complexes.

AB - Evidence for a transition state involving η2 co-ordination of a P-C bond to [Pd(dppe)] is obtained from an analysis of the insertion of [Pd(dppe)] fragments into (E)- and (Z)- [W(CO)5(PPh-CHPh-CHPh)] complexes.

U2 - 10.1039/C39890001389

DO - 10.1039/C39890001389

M3 - Article

AN - SCOPUS:37049089113

SN - 0022-4936

SP - 1389

EP - 1390

JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 18

ER -

Carmichael D, Hitchcock PB, Nixon JF, Mathey F, Ricard L. An η² transition state for the insertion of [Pd(dppe)] fragments into the phosphorus-carbon bonds of phosphiranepentacarbonyltungsten complexes. Crystal and molecular structures of (2R,3S,4R)- and (2R,3S,4S)-[Pd(dppe)(CHPhCHPhPPh)-W(CO)₅], dppe = 1,2-bis(diphenylphosphanyl)ethane. Journal of the Chemical Society, Chemical Communications. 1989 Jan 1;(18):1389-1390. doi: 10.1039/C39890001389