Asymmetric epoxidation of fujorinated allylic alcohols

C. Gosmini; T. Dubuffet; R. Sauvêtre; J. F. Normant

doi:10.1016/S0957-4166(00)82361-7

Asymmetric epoxidation of fujorinated allylic alcohols

C. Gosmini, T. Dubuffet, R. Sauvêtre, J. F. Normant

Laboratoire de Chimie des Organoélémentsniversité P. et M. Curie Tour

Research output: Contribution to journal › Article › peer-review

Abstract

The asymmetric epoxidation of an α,β-difluoro primary allylic alcohol, and of two α-fluoro secondary allylic alcohols follows the pattern known with non fluorinated analogs. The fluoro epoxides thus formed can be transformed into chiral α-ketols and into an α-fluoroacid.

Original language	English
Pages (from-to)	223-230
Number of pages	8
Journal	Tetrahedron Asymmetry
Volume	2
Issue number	3
DOIs	https://doi.org/10.1016/S0957-4166(00)82361-7
Publication status	Published - 1 Jan 1991
Externally published	Yes

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title = "Asymmetric epoxidation of fujorinated allylic alcohols",

abstract = "The asymmetric epoxidation of an α,β-difluoro primary allylic alcohol, and of two α-fluoro secondary allylic alcohols follows the pattern known with non fluorinated analogs. The fluoro epoxides thus formed can be transformed into chiral α-ketols and into an α-fluoroacid.",

author = "C. Gosmini and T. Dubuffet and R. Sauv{\^e}tre and Normant, \{J. F.\}",

year = "1991",

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T1 - Asymmetric epoxidation of fujorinated allylic alcohols

AU - Gosmini, C.

AU - Dubuffet, T.

AU - Sauvêtre, R.

AU - Normant, J. F.

PY - 1991/1/1

Y1 - 1991/1/1

N2 - The asymmetric epoxidation of an α,β-difluoro primary allylic alcohol, and of two α-fluoro secondary allylic alcohols follows the pattern known with non fluorinated analogs. The fluoro epoxides thus formed can be transformed into chiral α-ketols and into an α-fluoroacid.

AB - The asymmetric epoxidation of an α,β-difluoro primary allylic alcohol, and of two α-fluoro secondary allylic alcohols follows the pattern known with non fluorinated analogs. The fluoro epoxides thus formed can be transformed into chiral α-ketols and into an α-fluoroacid.

U2 - 10.1016/S0957-4166(00)82361-7

DO - 10.1016/S0957-4166(00)82361-7

M3 - Article

AN - SCOPUS:0025907469

SN - 0957-4166

VL - 2

SP - 223

EP - 230

JO - Tetrahedron Asymmetry

JF - Tetrahedron Asymmetry

IS - 3

ER -

Asymmetric epoxidation of fujorinated allylic alcohols

Abstract

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