Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI2

Arnaud Jaoul; Yan Yang; Nicolas Casaretto; Carine Clavaguéra; Laurent Maron; Grégory Nocton

doi:10.1039/d0cc05164k

Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI₂

Arnaud Jaoul
, Yan Yang
, Nicolas Casaretto
, Carine Clavaguéra
, Laurent Maron
, Grégory Nocton

Research output: Contribution to journal › Article › peer-review

Abstract

The use of stoechiometric SmI₂in combination with benzophenone and N-heterocyclic aromatics such as bipyridine, phenanthroline and pyridine allows the directortho-coupling of both partners in an atom economical reaction free of any other coupling additives. The transformation was investigated by¹H NMR, X-ray studies and theoretical calculations providing reaction intermediates and the reaction mechanism.

Original language	English
Pages (from-to)	11875-11878
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	79
DOIs	https://doi.org/10.1039/d0cc05164k
Publication status	Published - 11 Oct 2020
Externally published	Yes

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title = "Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI2",

abstract = "The use of stoechiometric SmI2in combination with benzophenone and N-heterocyclic aromatics such as bipyridine, phenanthroline and pyridine allows the directortho-coupling of both partners in an atom economical reaction free of any other coupling additives. The transformation was investigated by1H NMR, X-ray studies and theoretical calculations providing reaction intermediates and the reaction mechanism.",

author = "Arnaud Jaoul and Yan Yang and Nicolas Casaretto and Carine Clavagu{\'e}ra and Laurent Maron and Gr{\'e}gory Nocton",

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T1 - Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI2

AU - Jaoul, Arnaud

AU - Yang, Yan

AU - Casaretto, Nicolas

AU - Clavaguéra, Carine

AU - Maron, Laurent

AU - Nocton, Grégory

N1 - Publisher Copyright: © The Royal Society of Chemistry 2020.

PY - 2020/10/11

Y1 - 2020/10/11

N2 - The use of stoechiometric SmI2in combination with benzophenone and N-heterocyclic aromatics such as bipyridine, phenanthroline and pyridine allows the directortho-coupling of both partners in an atom economical reaction free of any other coupling additives. The transformation was investigated by1H NMR, X-ray studies and theoretical calculations providing reaction intermediates and the reaction mechanism.

AB - The use of stoechiometric SmI2in combination with benzophenone and N-heterocyclic aromatics such as bipyridine, phenanthroline and pyridine allows the directortho-coupling of both partners in an atom economical reaction free of any other coupling additives. The transformation was investigated by1H NMR, X-ray studies and theoretical calculations providing reaction intermediates and the reaction mechanism.

UR - https://www.scopus.com/pages/publications/85092251090

U2 - 10.1039/d0cc05164k

DO - 10.1039/d0cc05164k

M3 - Article

C2 - 33021260

AN - SCOPUS:85092251090

SN - 1359-7345

VL - 56

SP - 11875

EP - 11878

JO - Chemical Communications

JF - Chemical Communications

IS - 79

ER -

Atom economical coupling of benzophenone and N-heterocyclic aromatics with SmI₂

Abstract

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