Abstract
Considering the phenomenological electromagnetic description of optical activity, we establish a unified formal framework, wherein the gyration and permittivity tensors of any ordered medium (a molecule or a crystal) can be derived using the classic Born-Kuhn coupled oscillator model. This model allows for efficient parameterisation of both tensors in terms of configurational and structural parameters (orientations, positions and coupling strengths) of a system of coupled oscillators having the same symmetries as the medium of interest. Thus, Born-Kuhn molecular models of all optically active crystal classes are established.
| Original language | English |
|---|---|
| Pages (from-to) | 9094-9106 |
| Number of pages | 13 |
| Journal | Nanoscale |
| Volume | 17 |
| Issue number | 15 |
| DOIs | |
| Publication status | Published - 5 Mar 2025 |
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