Building a Lewis Acidic Phosphorus

Madelyn Qin Yi Tay; Yunpeng Lu; Rakesh Ganguly; Gilles Frison; Louis Ricard; Dragoslav Vidović; Duncan Carmichael

doi:10.1080/10426507.2014.980413

Building a Lewis Acidic Phosphorus

Madelyn Qin Yi Tay
, Yunpeng Lu
, Rakesh Ganguly
, Gilles Frison
, Louis Ricard
, Dragoslav Vidović
, Duncan Carmichael

Nanyang Technological University
CNRS

Research output: Contribution to journal › Article › peer-review

Abstract

Using the σ- and π-donating properties of carbodiphosphorane ligands, we recently synthesized a phosphorus (III)-containing dication. It is observed to undergo interesting reactivity with PMe₃, H₂O, and MeOH.

Original language	English
Pages (from-to)	785-788
Number of pages	4
Journal	Phosphorus, Sulfur and Silicon and Related Elements
Volume	190
Issue number	5-6
DOIs	https://doi.org/10.1080/10426507.2014.980413
Publication status	Published - 3 Jun 2015
Externally published	Yes

Keywords

Phosphenium
carbodiphosphoranes
dication
two-coordinate

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10.1080/10426507.2014.980413

Cite this

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title = "Building a Lewis Acidic Phosphorus",

abstract = "Using the σ- and π-donating properties of carbodiphosphorane ligands, we recently synthesized a phosphorus (III)-containing dication. It is observed to undergo interesting reactivity with PMe3, H2O, and MeOH.",

keywords = "Phosphenium, carbodiphosphoranes, dication, two-coordinate",

author = "Tay, \{Madelyn Qin Yi\} and Yunpeng Lu and Rakesh Ganguly and Gilles Frison and Louis Ricard and Dragoslav Vidovi{\'c} and Duncan Carmichael",

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year = "2015",

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doi = "10.1080/10426507.2014.980413",

language = "English",

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T1 - Building a Lewis Acidic Phosphorus

AU - Tay, Madelyn Qin Yi

AU - Lu, Yunpeng

AU - Ganguly, Rakesh

AU - Frison, Gilles

AU - Ricard, Louis

AU - Vidović, Dragoslav

AU - Carmichael, Duncan

PY - 2015/6/3

Y1 - 2015/6/3

N2 - Using the σ- and π-donating properties of carbodiphosphorane ligands, we recently synthesized a phosphorus (III)-containing dication. It is observed to undergo interesting reactivity with PMe3, H2O, and MeOH.

AB - Using the σ- and π-donating properties of carbodiphosphorane ligands, we recently synthesized a phosphorus (III)-containing dication. It is observed to undergo interesting reactivity with PMe3, H2O, and MeOH.

KW - Phosphenium

KW - carbodiphosphoranes

KW - dication

KW - two-coordinate

U2 - 10.1080/10426507.2014.980413

DO - 10.1080/10426507.2014.980413

M3 - Article

AN - SCOPUS:84953897510

SN - 1042-6507

VL - 190

SP - 785

EP - 788

JO - Phosphorus, Sulfur and Silicon and Related Elements

JF - Phosphorus, Sulfur and Silicon and Related Elements

IS - 5-6

ER -

Building a Lewis Acidic Phosphorus

Abstract

Keywords

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