C-H activation in strongly acidic media. the co-catalytic effect of the reaction medium

Mårten Ahlquist; Roy A. Periana; William A. Goddard

doi:10.1039/b821854d

C-H activation in strongly acidic media. the co-catalytic effect of the reaction medium

Mårten Ahlquist
, Roy A. Periana
, William A. Goddard

Materials and Process Simulation Center (139-74)
California Institute of Technology
Scripps Florida

Research output: Contribution to journal › Article › peer-review

63 Citations (Scopus)

Abstract

Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between Pt^II(bpym)Cl ₂ (bpym = 2,2′-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.

Original language	English
Pages (from-to)	2373-2375
Number of pages	3
Journal	Chemical Communications
Issue number	17
DOIs	https://doi.org/10.1039/b821854d
Publication status	Published - 1 Jan 2009
Externally published	Yes

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title = "C-H activation in strongly acidic media. the co-catalytic effect of the reaction medium",

abstract = "Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between PtII(bpym)Cl 2 (bpym = 2,2′-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.",

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AU - Ahlquist, Mårten

AU - Periana, Roy A.

AU - Goddard, William A.

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Y1 - 2009/1/1

N2 - Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between PtII(bpym)Cl 2 (bpym = 2,2′-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.

AB - Quantum mechanical (QM) results are used to establish the role of sulfuric acid solvent in facilitating the reaction between PtII(bpym)Cl 2 (bpym = 2,2′-bipyrimidinyl) and methane; coordination of methane to the platinum catalyst is found to be catalyzed by the acidic medium.

U2 - 10.1039/b821854d

DO - 10.1039/b821854d

M3 - Article

C2 - 19377690

AN - SCOPUS:65349188132

SN - 1359-7345

SP - 2373

EP - 2375

JO - Chemical Communications

JF - Chemical Communications

IS - 17

ER -

C-H activation in strongly acidic media. the co-catalytic effect of the reaction medium

Abstract

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