Charge Carrier Mobility in Poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine Composites with Electron Acceptor Molecules

Alexey R. Tameev; Alexey E. Aleksandrov; Ildar R. Sayarov; Sergey I. Pozin; Dmitry A. Lypenko; Artem V. Dmitriev; Natalia V. Nekrasova; Andrey Yu Chernyadyev; Aslan Yu Tsivadze

doi:10.3390/polym16050570

Charge Carrier Mobility in Poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine Composites with Electron Acceptor Molecules

Alexey R. Tameev, Alexey E. Aleksandrov, Ildar R. Sayarov, Sergey I. Pozin, Dmitry A. Lypenko, Artem V. Dmitriev, Natalia V. Nekrasova, Andrey Yu Chernyadyev, Aslan Yu Tsivadze

Russian Academy of Sciences

Research output: Contribution to journal › Article › peer-review

Abstract

Polymer composites based on poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine (poly-TPD) with PCBM and copper(II) pyropheophorbide derivative (Cu-PP) were developed. In thin films of the poly-TPD and Cu-PP composites, the charge carrier mobility was investigated for the first time. In the ternary poly-TPD:PCBM:Cu-PP composite, the electron and hole mobilities are the most balanced compared to binary composites and the photoconductivity is enhanced due to the sensitization by Cu-PP in blue and red spectral ranges. The new composites are promising for use in the development of photodetectors.

Original language	English
Article number	570
Journal	Polymers
Volume	16
Issue number	5
DOIs	https://doi.org/10.3390/polym16050570
Publication status	Published - 1 Mar 2024
Externally published	Yes

Keywords

CELIV
SCLC
charge carrier mobility
copper (II) pyropheophorbide
photoconductivity
poly-TPD
polymer composite

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10.3390/polym16050570

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@article{e4fb5bd8bf784289b40d749d56a7491d,

title = "Charge Carrier Mobility in Poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine Composites with Electron Acceptor Molecules",

abstract = "Polymer composites based on poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine (poly-TPD) with PCBM and copper(II) pyropheophorbide derivative (Cu-PP) were developed. In thin films of the poly-TPD and Cu-PP composites, the charge carrier mobility was investigated for the first time. In the ternary poly-TPD:PCBM:Cu-PP composite, the electron and hole mobilities are the most balanced compared to binary composites and the photoconductivity is enhanced due to the sensitization by Cu-PP in blue and red spectral ranges. The new composites are promising for use in the development of photodetectors.",

keywords = "CELIV, SCLC, charge carrier mobility, copper (II) pyropheophorbide, photoconductivity, poly-TPD, polymer composite",

author = "Tameev, \{Alexey R.\} and Aleksandrov, \{Alexey E.\} and Sayarov, \{Ildar R.\} and Pozin, \{Sergey I.\} and Lypenko, \{Dmitry A.\} and Dmitriev, \{Artem V.\} and Nekrasova, \{Natalia V.\} and Chernyadyev, \{Andrey Yu\} and Tsivadze, \{Aslan Yu\}",

note = "Publisher Copyright: {\textcopyright} 2024 by the authors.",

year = "2024",

month = mar,

day = "1",

doi = "10.3390/polym16050570",

language = "English",

volume = "16",

journal = "Polymers",

issn = "2073-4360",

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TY - JOUR

T1 - Charge Carrier Mobility in Poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine Composites with Electron Acceptor Molecules

AU - Tameev, Alexey R.

AU - Aleksandrov, Alexey E.

AU - Sayarov, Ildar R.

AU - Pozin, Sergey I.

AU - Lypenko, Dmitry A.

AU - Dmitriev, Artem V.

AU - Nekrasova, Natalia V.

AU - Chernyadyev, Andrey Yu

AU - Tsivadze, Aslan Yu

PY - 2024/3/1

Y1 - 2024/3/1

N2 - Polymer composites based on poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine (poly-TPD) with PCBM and copper(II) pyropheophorbide derivative (Cu-PP) were developed. In thin films of the poly-TPD and Cu-PP composites, the charge carrier mobility was investigated for the first time. In the ternary poly-TPD:PCBM:Cu-PP composite, the electron and hole mobilities are the most balanced compared to binary composites and the photoconductivity is enhanced due to the sensitization by Cu-PP in blue and red spectral ranges. The new composites are promising for use in the development of photodetectors.

AB - Polymer composites based on poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine (poly-TPD) with PCBM and copper(II) pyropheophorbide derivative (Cu-PP) were developed. In thin films of the poly-TPD and Cu-PP composites, the charge carrier mobility was investigated for the first time. In the ternary poly-TPD:PCBM:Cu-PP composite, the electron and hole mobilities are the most balanced compared to binary composites and the photoconductivity is enhanced due to the sensitization by Cu-PP in blue and red spectral ranges. The new composites are promising for use in the development of photodetectors.

KW - CELIV

KW - SCLC

KW - charge carrier mobility

KW - copper (II) pyropheophorbide

KW - photoconductivity

KW - poly-TPD

KW - polymer composite

UR - https://www.scopus.com/pages/publications/85187796583

U2 - 10.3390/polym16050570

DO - 10.3390/polym16050570

M3 - Article

AN - SCOPUS:85187796583

SN - 2073-4360

VL - 16

JO - Polymers

JF - Polymers

IS - 5

M1 - 570

ER -

Charge Carrier Mobility in Poly(N,N′-bis-4-butylphenyl-N,N′-bisphenyl)benzidine Composites with Electron Acceptor Molecules

Abstract

Keywords

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