Clusters dissolution of Yb 3+ in codoped SiO 2-Al 2O 3-P 2O 5 glass fiber and its relevance to photodarkening

T. Deschamps; N. Ollier; H. Vezin; C. Gonnet

doi:10.1063/1.3673792

Clusters dissolution of Yb ³⁺ in codoped SiO ₂-Al ₂O ₃-P ₂O ₅ glass fiber and its relevance to photodarkening

T. Deschamps
, N. Ollier
, H. Vezin
, C. Gonnet

Laboratoire des Solides Irradiés
Laboratoire de Spectrochimie Infrarouge et Raman, Université des Sciences et Technologies de Lille, UMR-CNRS 8516
Draka Comteq France SAS

Research output: Contribution to journal › Article › peer-review

Abstract

Using a combination of pulse electron paramagnetic resonance and photoluminescence spectroscopy, we demonstrate the major role of phosphorous rather than aluminium in the rare-earth dissolution process, an essential advance in telecommunication and solid laser fields. Our results also provide new insight into the micro-structural origin of the photodarkening process occurring in Yb doped fiber.

Original language	English
Article number	014503
Journal	Journal of Chemical Physics
Volume	136
Issue number	1
DOIs	https://doi.org/10.1063/1.3673792
Publication status	Published - 7 Jan 2012
Externally published	Yes

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abstract = "Using a combination of pulse electron paramagnetic resonance and photoluminescence spectroscopy, we demonstrate the major role of phosphorous rather than aluminium in the rare-earth dissolution process, an essential advance in telecommunication and solid laser fields. Our results also provide new insight into the micro-structural origin of the photodarkening process occurring in Yb doped fiber.",

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AU - Deschamps, T.

AU - Ollier, N.

AU - Vezin, H.

AU - Gonnet, C.

PY - 2012/1/7

Y1 - 2012/1/7

N2 - Using a combination of pulse electron paramagnetic resonance and photoluminescence spectroscopy, we demonstrate the major role of phosphorous rather than aluminium in the rare-earth dissolution process, an essential advance in telecommunication and solid laser fields. Our results also provide new insight into the micro-structural origin of the photodarkening process occurring in Yb doped fiber.

AB - Using a combination of pulse electron paramagnetic resonance and photoluminescence spectroscopy, we demonstrate the major role of phosphorous rather than aluminium in the rare-earth dissolution process, an essential advance in telecommunication and solid laser fields. Our results also provide new insight into the micro-structural origin of the photodarkening process occurring in Yb doped fiber.

U2 - 10.1063/1.3673792

DO - 10.1063/1.3673792

M3 - Article

AN - SCOPUS:84855522041

SN - 0021-9606

VL - 136

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 1

M1 - 014503

ER -

Clusters dissolution of Yb 3+ in codoped SiO 2-Al 2O 3-P 2O 5 glass fiber and its relevance to photodarkening

Abstract

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Clusters dissolution of Yb ³⁺ in codoped SiO ₂-Al ₂O ₃-P ₂O ₅ glass fiber and its relevance to photodarkening