Cobalt-catalysed Csp3-Csp3 cross-coupling of benzyl Katritzky pyridinium salts with Callyl-O electrophiles

Mengyu Gao; Corinne Gosmini

doi:10.1039/d4qo00402g

Cobalt-catalysed Csp³-Csp³ cross-coupling of benzyl Katritzky pyridinium salts with C_allyl-O electrophiles

Mengyu Gao
, Corinne Gosmini

CNRS

Research output: Contribution to journal › Article › peer-review

Abstract

Herein we report a Co-catalysed reductive cross-coupling to form Csp³-Csp³ bonds from two non-halogenated electrophiles, such as C-N and C-O bonds. This method provided different allylbenzyl derivatives in moderate to good yields under mild conditions from various functionalised benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates.

Original language	English
Pages (from-to)	3557-3561
Number of pages	5
Journal	Organic Chemistry Frontiers
Volume	11
Issue number	13
DOIs	https://doi.org/10.1039/d4qo00402g
Publication status	Published - 8 Apr 2024
Externally published	Yes

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title = "Cobalt-catalysed Csp3-Csp3 cross-coupling of benzyl Katritzky pyridinium salts with Callyl-O electrophiles",

abstract = "Herein we report a Co-catalysed reductive cross-coupling to form Csp3-Csp3 bonds from two non-halogenated electrophiles, such as C-N and C-O bonds. This method provided different allylbenzyl derivatives in moderate to good yields under mild conditions from various functionalised benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates.",

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AU - Gosmini, Corinne

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Y1 - 2024/4/8

N2 - Herein we report a Co-catalysed reductive cross-coupling to form Csp3-Csp3 bonds from two non-halogenated electrophiles, such as C-N and C-O bonds. This method provided different allylbenzyl derivatives in moderate to good yields under mild conditions from various functionalised benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates.

AB - Herein we report a Co-catalysed reductive cross-coupling to form Csp3-Csp3 bonds from two non-halogenated electrophiles, such as C-N and C-O bonds. This method provided different allylbenzyl derivatives in moderate to good yields under mild conditions from various functionalised benzyl Katritzky pyridinium salts and various allylic acetates, ethers or carbonates.

U2 - 10.1039/d4qo00402g

DO - 10.1039/d4qo00402g

M3 - Article

AN - SCOPUS:85190734651

SN - 2052-4110

VL - 11

SP - 3557

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JO - Organic Chemistry Frontiers

JF - Organic Chemistry Frontiers

IS - 13

ER -

Cobalt-catalysed Csp3-Csp3 cross-coupling of benzyl Katritzky pyridinium salts with Callyl-O electrophiles

Abstract

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Cobalt-catalysed Csp³-Csp³ cross-coupling of benzyl Katritzky pyridinium salts with C_allyl-O electrophiles