Cobalt-Catalyzed Csp3−Csp3Homocoupling

Yingxiao Cai; Xin Qian; Corinne Gosmini

doi:10.1002/adsc.201600213

Cobalt-Catalyzed C_sp3−C_sp3Homocoupling

Yingxiao Cai
, Xin Qian
, Corinne Gosmini

Université Paris-Saclay

Research output: Contribution to journal › Article › peer-review

29 Citations (Scopus)

Abstract

An efficient and easy method for C_sp³⁻C_sp³homocoupling was developed using cobalt bromide as catalyst. A series of functionalized alkyl bromides and alkyl chlorides were coupled in high yields under mild conditions. This reaction seems to involve a radical intermediate. (Figure presented.).

Original language	English
Pages (from-to)	2427-2430
Number of pages	4
Journal	Advanced Synthesis and Catalysis
Volume	358
Issue number	15
DOIs	https://doi.org/10.1002/adsc.201600213
Publication status	Published - 28 Jul 2016
Externally published	Yes

Keywords

alkyl-alkyl coupling
cobalt
dimerization
homocoupling
manganese

Access to Document

10.1002/adsc.201600213

Cite this

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title = "Cobalt-Catalyzed Csp3−Csp3Homocoupling",

abstract = "An efficient and easy method for Csp3−Csp3homocoupling was developed using cobalt bromide as catalyst. A series of functionalized alkyl bromides and alkyl chlorides were coupled in high yields under mild conditions. This reaction seems to involve a radical intermediate. (Figure presented.).",

keywords = "alkyl-alkyl coupling, cobalt, dimerization, homocoupling, manganese",

author = "Yingxiao Cai and Xin Qian and Corinne Gosmini",

note = "Publisher Copyright: {\textcopyright} 2016 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2016",

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T1 - Cobalt-Catalyzed Csp3−Csp3Homocoupling

AU - Cai, Yingxiao

AU - Qian, Xin

AU - Gosmini, Corinne

PY - 2016/7/28

Y1 - 2016/7/28

N2 - An efficient and easy method for Csp3−Csp3homocoupling was developed using cobalt bromide as catalyst. A series of functionalized alkyl bromides and alkyl chlorides were coupled in high yields under mild conditions. This reaction seems to involve a radical intermediate. (Figure presented.).

AB - An efficient and easy method for Csp3−Csp3homocoupling was developed using cobalt bromide as catalyst. A series of functionalized alkyl bromides and alkyl chlorides were coupled in high yields under mild conditions. This reaction seems to involve a radical intermediate. (Figure presented.).

KW - alkyl-alkyl coupling

KW - cobalt

KW - dimerization

KW - homocoupling

KW - manganese

U2 - 10.1002/adsc.201600213

DO - 10.1002/adsc.201600213

M3 - Article

AN - SCOPUS:84964746461

SN - 1615-4150

VL - 358

SP - 2427

EP - 2430

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 15