Abstract
Roles reversed: An efficient cobalt-catalyzed electrophilic amination of arylzinc reagents has been achieved. A variety of functionalized arylzincs and N-chloroamines were coupled under mild conditions (see scheme). Both secondary and tertiary arylamines were obtained in moderate to excellent yields.
| Original language | English |
|---|---|
| Pages (from-to) | 6225-6229 |
| Number of pages | 5 |
| Journal | Chemistry - A European Journal |
| Volume | 19 |
| Issue number | 20 |
| DOIs | |
| Publication status | Published - 10 May 2013 |
| Externally published | Yes |
Keywords
- C-N coupling
- amination
- anilines
- cobalt
- zinc
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