Cobalt-catalyzed reductive allylation of alkyl halides with allylic acetates or carbonates

Xin Qian; Audrey Auffrant; Abdellah Felouat; Corinne Gosmini

doi:10.1002/anie.201104390

Cobalt-catalyzed reductive allylation of alkyl halides with allylic acetates or carbonates

Xin Qian
, Audrey Auffrant
, Abdellah Felouat
, Corinne Gosmini

CNRS

Research output: Contribution to journal › Article › peer-review

Abstract

An efficient method for the direct allylation of alkyl halides catalyzed by simple cobalt(II) bromide has been developed. This reaction, using a variety of substituted allylic acetates or carbonates, provides the linear product as the major product. It displays broad substrate scope and good functional group tolerance.

Original language	English
Pages (from-to)	10402-10405
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	44
DOIs	https://doi.org/10.1002/anie.201104390
Publication status	Published - 24 Oct 2011
Externally published	Yes

Keywords

C-C coupling
alkyl halides
allylation
cobalt
homogeneous catalysis

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10.1002/anie.201104390

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title = "Cobalt-catalyzed reductive allylation of alkyl halides with allylic acetates or carbonates",

abstract = "An efficient method for the direct allylation of alkyl halides catalyzed by simple cobalt(II) bromide has been developed. This reaction, using a variety of substituted allylic acetates or carbonates, provides the linear product as the major product. It displays broad substrate scope and good functional group tolerance.",

keywords = "C-C coupling, alkyl halides, allylation, cobalt, homogeneous catalysis",

author = "Xin Qian and Audrey Auffrant and Abdellah Felouat and Corinne Gosmini",

year = "2011",

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day = "24",

doi = "10.1002/anie.201104390",

language = "English",

volume = "50",

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journal = "Angewandte Chemie - International Edition",

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T1 - Cobalt-catalyzed reductive allylation of alkyl halides with allylic acetates or carbonates

AU - Qian, Xin

AU - Auffrant, Audrey

AU - Felouat, Abdellah

AU - Gosmini, Corinne

PY - 2011/10/24

Y1 - 2011/10/24

N2 - An efficient method for the direct allylation of alkyl halides catalyzed by simple cobalt(II) bromide has been developed. This reaction, using a variety of substituted allylic acetates or carbonates, provides the linear product as the major product. It displays broad substrate scope and good functional group tolerance.

AB - An efficient method for the direct allylation of alkyl halides catalyzed by simple cobalt(II) bromide has been developed. This reaction, using a variety of substituted allylic acetates or carbonates, provides the linear product as the major product. It displays broad substrate scope and good functional group tolerance.

KW - C-C coupling

KW - alkyl halides

KW - allylation

KW - cobalt

KW - homogeneous catalysis

UR - https://www.scopus.com/pages/publications/80054968441

U2 - 10.1002/anie.201104390

DO - 10.1002/anie.201104390

M3 - Article

AN - SCOPUS:80054968441

SN - 1433-7851

VL - 50

SP - 10402

EP - 10405

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 44

ER -

Cobalt-catalyzed reductive allylation of alkyl halides with allylic acetates or carbonates

Abstract

Keywords

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