Collision-induced absorption in the v2 fundamental band of CH4. I. Determination of the quadrupole transition moment

R. H. Tipping; Alex Brown; Q. Ma; J. M. Hartmann; C. Boulet; J. Liévin

doi:10.1063/1.1408915

Collision-induced absorption in the v₂ fundamental band of CH₄. I. Determination of the quadrupole transition moment

R. H. Tipping
, Alex Brown
, Q. Ma
, J. M. Hartmann
, C. Boulet
, J. Liévin

Research output: Contribution to journal › Article › peer-review

Abstract

The vibrating quadrupole of CH₄ interacting with the polarizability of the perturber is proposed as another collision-induced dipole mechanism. This mechanism would be present for absorption in the v₂ region. For demonstration purposes, the simplest case of CH₄-Ar is considered.

Original language	English
Pages (from-to)	8852-8857
Number of pages	6
Journal	Journal of Chemical Physics
Volume	115
Issue number	19
DOIs	https://doi.org/10.1063/1.1408915
Publication status	Published - 15 Nov 2001

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title = "Collision-induced absorption in the v2 fundamental band of CH4. I. Determination of the quadrupole transition moment",

abstract = "The vibrating quadrupole of CH4 interacting with the polarizability of the perturber is proposed as another collision-induced dipole mechanism. This mechanism would be present for absorption in the v2 region. For demonstration purposes, the simplest case of CH4-Ar is considered.",

author = "Tipping, \{R. H.\} and Alex Brown and Q. Ma and Hartmann, \{J. M.\} and C. Boulet and J. Li{\'e}vin",

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AU - Tipping, R. H.

AU - Brown, Alex

AU - Ma, Q.

AU - Hartmann, J. M.

AU - Boulet, C.

AU - Liévin, J.

PY - 2001/11/15

Y1 - 2001/11/15

N2 - The vibrating quadrupole of CH4 interacting with the polarizability of the perturber is proposed as another collision-induced dipole mechanism. This mechanism would be present for absorption in the v2 region. For demonstration purposes, the simplest case of CH4-Ar is considered.

AB - The vibrating quadrupole of CH4 interacting with the polarizability of the perturber is proposed as another collision-induced dipole mechanism. This mechanism would be present for absorption in the v2 region. For demonstration purposes, the simplest case of CH4-Ar is considered.

U2 - 10.1063/1.1408915

DO - 10.1063/1.1408915

M3 - Article

AN - SCOPUS:0035890822

SN - 0021-9606

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JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 19

ER -

Collision-induced absorption in the v2 fundamental band of CH4. I. Determination of the quadrupole transition moment

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Collision-induced absorption in the v₂ fundamental band of CH₄. I. Determination of the quadrupole transition moment