Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

Madanakrishna Katari; Eleonore Payen De La Garanderie; Edith Nicol; Vincent Steinmetz; Guillaume Van Der Rest; Duncan Carmichael; Gilles Frison

doi:10.1039/c5cp01501d

Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

Madanakrishna Katari
, Eleonore Payen De La Garanderie
, Edith Nicol
, Vincent Steinmetz
, Guillaume Van Der Rest
, Duncan Carmichael
, Gilles Frison

CNRS
Université Paris-Sud 11

Research output: Contribution to journal › Article › peer-review

Abstract

Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono-ligated complex has been demonstrated.

Original language	English
Pages (from-to)	25689-25692
Number of pages	4
Journal	Physical Chemistry Chemical Physics
Volume	17
Issue number	39
DOIs	https://doi.org/10.1039/c5cp01501d
Publication status	Published - 29 May 2015
Externally published	Yes

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10.1039/c5cp01501d

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Katari, M., De La Garanderie, E. P., Nicol, E., Steinmetz, V., Van Der Rest, G., Carmichael, D., & Frison, G. (2015). Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand. Physical Chemistry Chemical Physics, 17(39), 25689-25692. https://doi.org/10.1039/c5cp01501d

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title = "Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand",

abstract = "Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono-ligated complex has been demonstrated.",

author = "Madanakrishna Katari and \{De La Garanderie\}, \{Eleonore Payen\} and Edith Nicol and Vincent Steinmetz and \{Van Der Rest\}, Guillaume and Duncan Carmichael and Gilles Frison",

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year = "2015",

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doi = "10.1039/c5cp01501d",

language = "English",

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Katari, M, De La Garanderie, EP, Nicol, E, Steinmetz, V, Van Der Rest, G, Carmichael, D & Frison, G 2015, 'Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand', Physical Chemistry Chemical Physics, vol. 17, no. 39, pp. 25689-25692. https://doi.org/10.1039/c5cp01501d

Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand. / Katari, Madanakrishna; De La Garanderie, Eleonore Payen; Nicol, Edith et al.
In: Physical Chemistry Chemical Physics, Vol. 17, No. 39, 29.05.2015, p. 25689-25692.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

AU - Katari, Madanakrishna

AU - De La Garanderie, Eleonore Payen

AU - Nicol, Edith

AU - Steinmetz, Vincent

AU - Van Der Rest, Guillaume

AU - Carmichael, Duncan

AU - Frison, Gilles

PY - 2015/5/29

Y1 - 2015/5/29

N2 - Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono-ligated complex has been demonstrated.

AB - Combining electron capture dissociation mass spectrometry and infrared multiple photon dissociation action spectroscopy allows the formation, selection and characterisation of reduced metal complexes containing non-innocent ligands. Zinc complexes containing diazafluorenone ligands have been studied and the localisation of the single electron on the metal atom in the mono-ligated complex has been demonstrated.

U2 - 10.1039/c5cp01501d

DO - 10.1039/c5cp01501d

M3 - Article

AN - SCOPUS:84942766421

SN - 1463-9076

VL - 17

SP - 25689

EP - 25692

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 39

ER -

Combining gas phase electron capture and IRMPD action spectroscopy to probe the electronic structure of a metastable reduced organometallic complex containing a non-innocent ligand

Abstract

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