Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

G. Cabochea; J. F. Hochepied; P. Piccardo; K. P. Rzybylski; R. Ruckdäschel; M. R. Ardigó; E. Fatome; S. Chevalier; A. Perron; L. Combemale; M. Palard; J. Prazuch; T. Brylewski

doi:10.1149/1.3205593

Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

G. Cabochea
, J. F. Hochepied
, P. Piccardo
, K. P. Rzybylski
, R. Ruckdäschel
, M. R. Ardigó
, E. Fatome
, S. Chevalier
, A. Perron
, L. Combemale
, M. Palard
, J. Prazuch
, T. Brylewski

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La _0.60Sr_0.40CoO_3-δ (LSCF40) or La _0.60Sr_0.40Co_0.20Fe_0.80O _3-δ (LSCF48); electrolyte materials are: Ce _0.85Y_0.15O_2-δ (YDC15) and BaCe _0.85Y_0.15O_3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO₄ formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.

Original language	English
Title of host publication	ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)
Pages	763-772
Number of pages	10
Edition	2 PART 1
DOIs	https://doi.org/10.1149/1.3205593
Publication status	Published - 1 Dec 2009
Externally published	Yes
Event	11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting - Vienna, Austria Duration: 4 Oct 2009 → 9 Oct 2009

Publication series

Name	ECS Transactions
Number	2 PART 1
Volume	25
ISSN (Print)	1938-5862
ISSN (Electronic)	1938-6737

Conference

Conference	11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting
Country/Territory	Austria
City	Vienna
Period	4/10/09 → 9/10/09

Access to Document

10.1149/1.3205593

Cite this

Cabochea, G., Hochepied, J. F., Piccardo, P., Rzybylski, K. P., Ruckdäschel, R., Ardigó, M. R., Fatome, E., Chevalier, S., Perron, A., Combemale, L., Palard, M., Prazuch, J., & Brylewski, T. (2009). Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design. In ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI) (2 PART 1 ed., pp. 763-772). (ECS Transactions; Vol. 25, No. 2 PART 1). https://doi.org/10.1149/1.3205593

@inproceedings{0c346bd9bb604fea8a94e4a5c6284d18,

title = "Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design",

abstract = "The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La 0.60Sr0.40CoO3-δ (LSCF40) or La 0.60Sr0.40Co0.20Fe0.80O 3-δ (LSCF48); electrolyte materials are: Ce 0.85Y0.15O2-δ (YDC15) and BaCe 0.85Y0.15O3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO4 formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.",

author = "G. Cabochea and Hochepied, \{J. F.\} and P. Piccardo and Rzybylski, \{K. P.\} and R. Ruckd{\"a}schel and Ardig{\'o}, \{M. R.\} and E. Fatome and S. Chevalier and A. Perron and L. Combemale and M. Palard and J. Prazuch and T. Brylewski",

year = "2009",

month = dec,

day = "1",

doi = "10.1149/1.3205593",

language = "English",

isbn = "9781566777391",

series = "ECS Transactions",

number = "2 PART 1",

pages = "763--772",

booktitle = "ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)",

edition = "2 PART 1",

note = "11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting ; Conference date: 04-10-2009 Through 09-10-2009",

}

Cabochea, G, Hochepied, JF, Piccardo, P, Rzybylski, KP, Ruckdäschel, R, Ardigó, MR, Fatome, E, Chevalier, S, Perron, A, Combemale, L, Palard, M, Prazuch, J & Brylewski, T 2009, Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design. in ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI). 2 PART 1 edn, ECS Transactions, no. 2 PART 1, vol. 25, pp. 763-772, 11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting, Vienna, Austria, 4/10/09. https://doi.org/10.1149/1.3205593

Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design. / Cabochea, G.; Hochepied, J. F.; Piccardo, P. et al.
ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI). 2 PART 1. ed. 2009. p. 763-772 (ECS Transactions; Vol. 25, No. 2 PART 1).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

AU - Cabochea, G.

AU - Hochepied, J. F.

AU - Piccardo, P.

AU - Rzybylski, K. P.

AU - Ruckdäschel, R.

AU - Ardigó, M. R.

AU - Fatome, E.

AU - Chevalier, S.

AU - Perron, A.

AU - Combemale, L.

AU - Palard, M.

AU - Prazuch, J.

AU - Brylewski, T.

PY - 2009/12/1

Y1 - 2009/12/1

N2 - The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La 0.60Sr0.40CoO3-δ (LSCF40) or La 0.60Sr0.40Co0.20Fe0.80O 3-δ (LSCF48); electrolyte materials are: Ce 0.85Y0.15O2-δ (YDC15) and BaCe 0.85Y0.15O3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO4 formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.

AB - The IDEAL-Cell project aims at developing an innovative and competitive concept for fuel cell operating between 600-700°C. It is based on the junction between a PCFC anode/electrolyte part and a SOFC electrolyte/cathode, through a mixed porous ceramic membrane. Cathode materials are: La 0.60Sr0.40CoO3-δ (LSCF40) or La 0.60Sr0.40Co0.20Fe0.80O 3-δ (LSCF48); electrolyte materials are: Ce 0.85Y0.15O2-δ (YDC15) and BaCe 0.85Y0.15O3-δ (BCY15). Ni-BCY15 cermet is the anode material. The central membrane is made of BCY15-YDC15 mixture. Good compatibility was observed at electrode/electrolyte cathode interface after long term ageing (20 h/1100°C following by 500 h/700°C) and no new phase was detected. Concerning the dual membrane BCY15-YDC15, a good adhesion was obtained between these two electrolyte materials. Finally, reactivity between LSCF40/48 and Crofer 22 APU (selected as first generation interconnect material) was studied in oxidizing atmosphere (1 h/1000°C following by 200 h/700°C). SrCrO4 formation was observed due to the diffusion of Cr and reaction with Sr from the cathode material.

UR - https://www.scopus.com/pages/publications/77649247227

U2 - 10.1149/1.3205593

DO - 10.1149/1.3205593

M3 - Conference contribution

AN - SCOPUS:77649247227

SN - 9781566777391

T3 - ECS Transactions

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BT - ECS Transactions - Solid Oxide Fuel Cells 11 (SOFC-XI)

T2 - 11th International Symposium on Solid Oxide Fuel Cells (SOFC-XI)- 216th ECS Meeting

Y2 - 4 October 2009 through 9 October 2009

ER -

Compatibility and reactivity between materials in an innovative dual membrane fuel-cell (IDEAL-Cell) design

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