Concise synthesis of enantiopure (S)-(+)-2,2'-bis(tert-butyldimethylsilyl)- 1,1'-diphosphaferrocene: Anion-dependence of its coordination to palladium(II) centers

Yves Cabon; Duncan Carmichael; Xavier Frédéric Le Goff

doi:10.1021/om800009e

Concise synthesis of enantiopure (S)-(+)-2,2'-bis(tert-butyldimethylsilyl)- 1,1'-diphosphaferrocene: Anion-dependence of its coordination to palladium(II) centers

Yves Cabon
, Duncan Carmichael
, Xavier Frédéric Le Goff

CNRS

Research output: Contribution to journal › Article › peer-review

Abstract

A convenient synthesis of enantiopure (S)-(+)-2,2'-bis(tert- butyldimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-diphospha-ferrocene is described. The compound shows unusual coordination properties with respect to Otsuka's Pd(II) dimer di-(S)-chloro-[1-[1-(dimethylamino)ethyl]-2-naphthyl-C,N]palla- dium(II)].

Original language	English
Pages (from-to)	370-373
Number of pages	4
Journal	Organometallics
Volume	28
Issue number	1
DOIs	https://doi.org/10.1021/om800009e
Publication status	Published - 12 Jan 2009
Externally published	Yes

Access to Document

10.1021/om800009e

Cite this

@article{8f54d170ad6e44378c5ca137608fe0b3,

title = "Concise synthesis of enantiopure (S)-(+)-2,2'-bis(tert-butyldimethylsilyl)- 1,1'-diphosphaferrocene: Anion-dependence of its coordination to palladium(II) centers",

abstract = "A convenient synthesis of enantiopure (S)-(+)-2,2'-bis(tert- butyldimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-diphospha-ferrocene is described. The compound shows unusual coordination properties with respect to Otsuka's Pd(II) dimer di-(S)-chloro-[1-[1-(dimethylamino)ethyl]-2-naphthyl-C,N]palla- dium(II)].",

author = "Yves Cabon and Duncan Carmichael and \{Le Goff\}, \{Xavier Fr{\'e}d{\'e}ric\}",

year = "2009",

month = jan,

day = "12",

doi = "10.1021/om800009e",

language = "English",

volume = "28",

pages = "370--373",

journal = "Organometallics",

issn = "0276-7333",

number = "1",

}

TY - JOUR

T1 - Concise synthesis of enantiopure (S)-(+)-2,2'-bis(tert-butyldimethylsilyl)- 1,1'-diphosphaferrocene

T2 - Anion-dependence of its coordination to palladium(II) centers

AU - Cabon, Yves

AU - Carmichael, Duncan

AU - Le Goff, Xavier Frédéric

PY - 2009/1/12

Y1 - 2009/1/12

N2 - A convenient synthesis of enantiopure (S)-(+)-2,2'-bis(tert- butyldimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-diphospha-ferrocene is described. The compound shows unusual coordination properties with respect to Otsuka's Pd(II) dimer di-(S)-chloro-[1-[1-(dimethylamino)ethyl]-2-naphthyl-C,N]palla- dium(II)].

AB - A convenient synthesis of enantiopure (S)-(+)-2,2'-bis(tert- butyldimethylsilyl)-3,3',4,4'-tetramethyl-1,1'-diphospha-ferrocene is described. The compound shows unusual coordination properties with respect to Otsuka's Pd(II) dimer di-(S)-chloro-[1-[1-(dimethylamino)ethyl]-2-naphthyl-C,N]palla- dium(II)].

U2 - 10.1021/om800009e

DO - 10.1021/om800009e

M3 - Article

AN - SCOPUS:61849161589

SN - 0276-7333

VL - 28

SP - 370

EP - 373

JO - Organometallics

JF - Organometallics

IS - 1

ER -

Concise synthesis of enantiopure (S)-(+)-2,2'-bis(tert-butyldimethylsilyl)- 1,1'-diphosphaferrocene: Anion-dependence of its coordination to palladium(II) centers

Abstract

Access to Document

Fingerprint

Cite this