Controlled radical polymerization in dispersed media

D. Charmot; P. Corpart; H. Adam; S. Z. Zard; T. Biadatti; G. Bouhadir

doi:10.1002/1521-3900(200002)150:1<23::AID-MASY23>3.0.CO;2-E

Controlled radical polymerization in dispersed media

D. Charmot
, P. Corpart
, H. Adam
, S. Z. Zard
, T. Biadatti
, G. Bouhadir

Rhodia Recherches

Research output: Contribution to journal › Article › peer-review

Abstract

Free radical degenerative transfer promoted by dithiocarbonate groups is the basis of a new method for controlled free radical polymerization (MADIX). Thus, certain alkyl xanthates are used to impart livingness to radical polymerization of styrene, acrylates and vinyl acetate. Among other analytical methods, MALDI-TOF mass spectrometry showed unambiguously the living character of the process. The MADIX technique was implemented in emulsion polymerization straightforwardly with no retardation effects and an excellent fit between experimental and theoretical molecular weights.

Original language	English
Pages (from-to)	23-32
Number of pages	10
Journal	Macromolecular Symposia
Volume	150
DOIs	https://doi.org/10.1002/1521-3900(200002)150:1<23::AID-MASY23>3.0.CO;2-E
Publication status	Published - 1 Jan 2000
Externally published	Yes

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title = "Controlled radical polymerization in dispersed media",

abstract = "Free radical degenerative transfer promoted by dithiocarbonate groups is the basis of a new method for controlled free radical polymerization (MADIX). Thus, certain alkyl xanthates are used to impart livingness to radical polymerization of styrene, acrylates and vinyl acetate. Among other analytical methods, MALDI-TOF mass spectrometry showed unambiguously the living character of the process. The MADIX technique was implemented in emulsion polymerization straightforwardly with no retardation effects and an excellent fit between experimental and theoretical molecular weights.",

author = "D. Charmot and P. Corpart and H. Adam and Zard, \{S. Z.\} and T. Biadatti and G. Bouhadir",

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T1 - Controlled radical polymerization in dispersed media

AU - Charmot, D.

AU - Corpart, P.

AU - Adam, H.

AU - Zard, S. Z.

AU - Biadatti, T.

AU - Bouhadir, G.

PY - 2000/1/1

Y1 - 2000/1/1

N2 - Free radical degenerative transfer promoted by dithiocarbonate groups is the basis of a new method for controlled free radical polymerization (MADIX). Thus, certain alkyl xanthates are used to impart livingness to radical polymerization of styrene, acrylates and vinyl acetate. Among other analytical methods, MALDI-TOF mass spectrometry showed unambiguously the living character of the process. The MADIX technique was implemented in emulsion polymerization straightforwardly with no retardation effects and an excellent fit between experimental and theoretical molecular weights.

AB - Free radical degenerative transfer promoted by dithiocarbonate groups is the basis of a new method for controlled free radical polymerization (MADIX). Thus, certain alkyl xanthates are used to impart livingness to radical polymerization of styrene, acrylates and vinyl acetate. Among other analytical methods, MALDI-TOF mass spectrometry showed unambiguously the living character of the process. The MADIX technique was implemented in emulsion polymerization straightforwardly with no retardation effects and an excellent fit between experimental and theoretical molecular weights.

U2 - 10.1002/1521-3900(200002)150:1<23::AID-MASY23>3.0.CO;2-E

DO - 10.1002/1521-3900(200002)150:1<23::AID-MASY23>3.0.CO;2-E

M3 - Article

AN - SCOPUS:0033646992

SN - 1022-1360

VL - 150

SP - 23

EP - 32

JO - Macromolecular Symposia

JF - Macromolecular Symposia

ER -

Controlled radical polymerization in dispersed media

Abstract

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