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Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site

  • Fenfen Xu
  • , Cédric Tard
  • , Xiufeng Wang
  • , Saad K. Ibrahim
  • , David L. Hughes
  • , Wei Zhong
  • , Xirui Zeng
  • , Qiuyan Luo
  • , Xiaoming Liu
  • , Christopher J. Pickett
  • Department of Chemistry
  • Nanchang University
  • University of East Anglia
  • School of Chemistry and Chemical Engineering
  • Jinggangshan University

Research output: Contribution to journal › Article › peer-review

14 Citations (Scopus)

Abstract

Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially 'switched-on' via a ligand protonation pathway which is competitive with metal-metal bond protonation.

Original languageEnglish
Pages (from-to)606-608
Number of pages3
JournalChemical Communications
Volume8
Issue number5
DOIs
Publication statusPublished - 1 Jan 2002
Externally publishedYes

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