CO2 activation by electrogenerated divalent samarium for aryl halide carboxylation

Sakna Bazzi; Gaëtan Le Duc; Emmanuelle Schulz; Corinne Gosmini; Mohamed Mellah

doi:10.1039/c9ob01752f

CO₂ activation by electrogenerated divalent samarium for aryl halide carboxylation

Sakna Bazzi
, Gaëtan Le Duc
, Emmanuelle Schulz
, Corinne Gosmini
, Mohamed Mellah

Institut de Chimie Moléculaire et des Matériaux d'Orsay
CNRS

Research output: Contribution to journal › Article › peer-review

Abstract

The reductive carboxylation of aryl halides has been investigated using a samarium electrode as a sacrificial anode to yield the corresponding benzoic acids, providing a smooth strategy for CO₂ activation. Carboxylation occurred after an efficient reduction of carbon dioxide mediated by an electrogenerated Sm(ii)-complex acting as a strong monoelectronic reductive reagent.

Original language	English
Pages (from-to)	8546-8550
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	17
Issue number	37
DOIs	https://doi.org/10.1039/c9ob01752f
Publication status	Published - 1 Jan 2019
Externally published	Yes

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title = "CO2 activation by electrogenerated divalent samarium for aryl halide carboxylation",

abstract = "The reductive carboxylation of aryl halides has been investigated using a samarium electrode as a sacrificial anode to yield the corresponding benzoic acids, providing a smooth strategy for CO2 activation. Carboxylation occurred after an efficient reduction of carbon dioxide mediated by an electrogenerated Sm(ii)-complex acting as a strong monoelectronic reductive reagent.",

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AU - Bazzi, Sakna

AU - Le Duc, Gaëtan

AU - Schulz, Emmanuelle

AU - Gosmini, Corinne

AU - Mellah, Mohamed

N1 - Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2019/1/1

Y1 - 2019/1/1

N2 - The reductive carboxylation of aryl halides has been investigated using a samarium electrode as a sacrificial anode to yield the corresponding benzoic acids, providing a smooth strategy for CO2 activation. Carboxylation occurred after an efficient reduction of carbon dioxide mediated by an electrogenerated Sm(ii)-complex acting as a strong monoelectronic reductive reagent.

AB - The reductive carboxylation of aryl halides has been investigated using a samarium electrode as a sacrificial anode to yield the corresponding benzoic acids, providing a smooth strategy for CO2 activation. Carboxylation occurred after an efficient reduction of carbon dioxide mediated by an electrogenerated Sm(ii)-complex acting as a strong monoelectronic reductive reagent.

UR - https://www.scopus.com/pages/publications/85072628009

U2 - 10.1039/c9ob01752f

DO - 10.1039/c9ob01752f

M3 - Article

C2 - 31528934

AN - SCOPUS:85072628009

SN - 1477-0520

VL - 17

SP - 8546

EP - 8550

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

IS - 37

ER -

CO₂ activation by electrogenerated divalent samarium for aryl halide carboxylation

Abstract

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