Crystal structure of 2-[chloro(4-methoxyphenyl)methyl]-2-(4-methoxyphenyl)-5,5-dimethylcyclohexane-1,3-dione

Saloua Chelli; Konstantin Troshin; Sami Lakhdar; Herbert Mayr; Peter Mayer

doi:10.1107/S2056989016002085

Crystal structure of 2-[chloro(4-methoxyphenyl)methyl]-2-(4-methoxyphenyl)-5,5-dimethylcyclohexane-1,3-dione

Saloua Chelli
, Konstantin Troshin
, Sami Lakhdar
, Herbert Mayr
, Peter Mayer

Universität München

Research output: Contribution to journal › Article › peer-review

2 Citations (Scopus)

Abstract

In the title compound, C23H25ClO4, the cyclohexane ring adopts a chair conformation with the 4-methoxyphenyl substituent in an axial position and the chloro(4-methoxyphenyl)methyl substituent in an equatorial position. The packing features inversion dimers formed by pairs of C-H⋯O contacts and strands along [100] and [010] established by further C-H⋯O and C-H⋯Cl contacts, respectively.

Original language	English
Pages (from-to)	300-303
Number of pages	4
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	72
DOIs	https://doi.org/10.1107/S2056989016002085
Publication status	Published - 1 Jan 2016
Externally published	Yes

Keywords

crystal structure
weak C-H⋯O and C-H⋯Cl interactions

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10.1107/S2056989016002085

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title = "Crystal structure of 2-[chloro(4-methoxyphenyl)methyl]-2-(4-methoxyphenyl)-5,5-dimethylcyclohexane-1,3-dione",

abstract = "In the title compound, C23H25ClO4, the cyclohexane ring adopts a chair conformation with the 4-methoxyphenyl substituent in an axial position and the chloro(4-methoxyphenyl)methyl substituent in an equatorial position. The packing features inversion dimers formed by pairs of C-H⋯O contacts and strands along [100] and [010] established by further C-H⋯O and C-H⋯Cl contacts, respectively.",

keywords = "crystal structure, weak C-H⋯O and C-H⋯Cl interactions",

author = "Saloua Chelli and Konstantin Troshin and Sami Lakhdar and Herbert Mayr and Peter Mayer",

note = "Publisher Copyright: {\textcopyright} 2016 Chelli et al.",

year = "2016",

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day = "1",

doi = "10.1107/S2056989016002085",

language = "English",

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journal = "Acta Crystallographica Section E: Crystallographic Communications",

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TY - JOUR

T1 - Crystal structure of 2-[chloro(4-methoxyphenyl)methyl]-2-(4-methoxyphenyl)-5,5-dimethylcyclohexane-1,3-dione

AU - Chelli, Saloua

AU - Troshin, Konstantin

AU - Lakhdar, Sami

AU - Mayr, Herbert

AU - Mayer, Peter

PY - 2016/1/1

Y1 - 2016/1/1

N2 - In the title compound, C23H25ClO4, the cyclohexane ring adopts a chair conformation with the 4-methoxyphenyl substituent in an axial position and the chloro(4-methoxyphenyl)methyl substituent in an equatorial position. The packing features inversion dimers formed by pairs of C-H⋯O contacts and strands along [100] and [010] established by further C-H⋯O and C-H⋯Cl contacts, respectively.

AB - In the title compound, C23H25ClO4, the cyclohexane ring adopts a chair conformation with the 4-methoxyphenyl substituent in an axial position and the chloro(4-methoxyphenyl)methyl substituent in an equatorial position. The packing features inversion dimers formed by pairs of C-H⋯O contacts and strands along [100] and [010] established by further C-H⋯O and C-H⋯Cl contacts, respectively.

KW - crystal structure

KW - weak C-H⋯O and C-H⋯Cl interactions

UR - https://www.scopus.com/pages/publications/84960131339

U2 - 10.1107/S2056989016002085

DO - 10.1107/S2056989016002085

M3 - Article

AN - SCOPUS:84960131339

SN - 2056-9890

VL - 72

SP - 300

EP - 303

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

ER -

Crystal structure of 2-[chloro(4-methoxyphenyl)methyl]-2-(4-methoxyphenyl)-5,5-dimethylcyclohexane-1,3-dione

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Keywords

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